Fluorescence detecting of carbazole-containing poly(phenyleneethynylene)'s thin film to TNT volatile

Yang Liu; Jun Ge Zhi; Jian Bing Shi; Bin Tong; Yu Ping Dong

doi:10.3788/fgxb20123301.0102

Fluorescence detecting of carbazole-containing poly(phenyleneethynylene)'s thin film to TNT volatile

Yang Liu, Jun Ge Zhi^*, Jian Bing Shi, Bin Tong, Yu Ping Dong

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

Poly(phenylene ethynylene) containing carbazole unit in the main-chain (PPECz) was synthesized by Pd-catalyzed Sonogashira coupling reaction between 3,6-dibromo-9-octylcarbazole and 2,5-dimethoxy-1,4-diethynylbenzene. PPECz in the solution and thin film exhibits obvious luminescence properties, which can be used to detect TNT sensitively. The fluorescence intensity of PPECz thin-film can be quenched 56% by the volatile of 40 μg TNT solid at 60 s at normal atmospheric temperature and pressure. This strategy can provide a platform for developing highly sensitive and efficient chemo sensors for warfare explosives.

Original language	English
Pages (from-to)	102-108
Number of pages	7
Journal	Chinese Journal of Luminescence
Volume	33
Issue number	1
DOIs	https://doi.org/10.3788/fgxb20123301.0102
Publication status	Published - Jan 2012

Keywords

Carbazole
Fluorescence quenching
Poly(phenylene ethynylene)
TNT volatile

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@article{a53cb88cd2e247f887b247b052159869,

title = "Fluorescence detecting of carbazole-containing poly(phenyleneethynylene)'s thin film to TNT volatile",

abstract = "Poly(phenylene ethynylene) containing carbazole unit in the main-chain (PPECz) was synthesized by Pd-catalyzed Sonogashira coupling reaction between 3,6-dibromo-9-octylcarbazole and 2,5-dimethoxy-1,4-diethynylbenzene. PPECz in the solution and thin film exhibits obvious luminescence properties, which can be used to detect TNT sensitively. The fluorescence intensity of PPECz thin-film can be quenched 56% by the volatile of 40 μg TNT solid at 60 s at normal atmospheric temperature and pressure. This strategy can provide a platform for developing highly sensitive and efficient chemo sensors for warfare explosives.",

keywords = "Carbazole, Fluorescence quenching, Poly(phenylene ethynylene), TNT volatile",

author = "Yang Liu and Zhi, {Jun Ge} and Shi, {Jian Bing} and Bin Tong and Dong, {Yu Ping}",

year = "2012",

month = jan,

doi = "10.3788/fgxb20123301.0102",

language = "English",

volume = "33",

pages = "102--108",

journal = "Chinese Journal of Luminescence",

issn = "1000-7032",

publisher = "Chines Academy of Sciences",

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TY - JOUR

T1 - Fluorescence detecting of carbazole-containing poly(phenyleneethynylene)'s thin film to TNT volatile

AU - Liu, Yang

AU - Zhi, Jun Ge

AU - Shi, Jian Bing

AU - Tong, Bin

AU - Dong, Yu Ping

PY - 2012/1

Y1 - 2012/1

N2 - Poly(phenylene ethynylene) containing carbazole unit in the main-chain (PPECz) was synthesized by Pd-catalyzed Sonogashira coupling reaction between 3,6-dibromo-9-octylcarbazole and 2,5-dimethoxy-1,4-diethynylbenzene. PPECz in the solution and thin film exhibits obvious luminescence properties, which can be used to detect TNT sensitively. The fluorescence intensity of PPECz thin-film can be quenched 56% by the volatile of 40 μg TNT solid at 60 s at normal atmospheric temperature and pressure. This strategy can provide a platform for developing highly sensitive and efficient chemo sensors for warfare explosives.

AB - Poly(phenylene ethynylene) containing carbazole unit in the main-chain (PPECz) was synthesized by Pd-catalyzed Sonogashira coupling reaction between 3,6-dibromo-9-octylcarbazole and 2,5-dimethoxy-1,4-diethynylbenzene. PPECz in the solution and thin film exhibits obvious luminescence properties, which can be used to detect TNT sensitively. The fluorescence intensity of PPECz thin-film can be quenched 56% by the volatile of 40 μg TNT solid at 60 s at normal atmospheric temperature and pressure. This strategy can provide a platform for developing highly sensitive and efficient chemo sensors for warfare explosives.

KW - Carbazole

KW - Fluorescence quenching

KW - Poly(phenylene ethynylene)

KW - TNT volatile

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U2 - 10.3788/fgxb20123301.0102

DO - 10.3788/fgxb20123301.0102

M3 - Article

AN - SCOPUS:84863077729

SN - 1000-7032

VL - 33

SP - 102

EP - 108

JO - Chinese Journal of Luminescence

JF - Chinese Journal of Luminescence

IS - 1

ER -

Fluorescence detecting of carbazole-containing poly(phenyleneethynylene)'s thin film to TNT volatile

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