Fe/Ni Metal-Organic Frameworks and Their Binder-Free Thin Films for Efficient Oxygen Evolution with Low Overpotential

Lu Wang; Yizhen Wu; Rui Cao; Lantian Ren; Mingxing Chen; Xiao Feng; Junwen Zhou; Bo Wang

doi:10.1021/acsami.6b05375

Fe/Ni Metal-Organic Frameworks and Their Binder-Free Thin Films for Efficient Oxygen Evolution with Low Overpotential

Lu Wang, Yizhen Wu, Rui Cao, Lantian Ren, Mingxing Chen, Xiao Feng, Junwen Zhou, Bo Wang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

207 Citations (Scopus)

Abstract

Multivariate metal-organic frameworks with active Fe/Ni building blocks that are spatially arranged in an open structure are synthesized and explored for oxygen evolution reaction. The heterogeneity and porosity of this system prove to show synergy effect and give low onset overpotential at 170 mV. These MOFs are further fabricated into thin films over nickel foam by controlled electrochemical deposition to improve the surface conductivity and the overall stability. The Fe/Ni metal-organic framework film exhibits outstanding electrocatalytic activity with low overpotential of 270 mV at 10 mA cm^-2, small Tafel slope, high Faradaic efficiency, high turnover frequency, and great stability.

Original language	English
Pages (from-to)	16736-16743
Number of pages	8
Journal	ACS applied materials & interfaces
Volume	8
Issue number	26
DOIs	https://doi.org/10.1021/acsami.6b05375
Publication status	Published - 6 Jul 2016

Keywords

binder-free film
electrocatalysis
electrochemical deposition
metal-organic frameworks
oxygen evolution reaction

Access to Document

10.1021/acsami.6b05375

Cite this

@article{97e66f85f2144f398ccc574c126fdf4c,

title = "Fe/Ni Metal-Organic Frameworks and Their Binder-Free Thin Films for Efficient Oxygen Evolution with Low Overpotential",

abstract = "Multivariate metal-organic frameworks with active Fe/Ni building blocks that are spatially arranged in an open structure are synthesized and explored for oxygen evolution reaction. The heterogeneity and porosity of this system prove to show synergy effect and give low onset overpotential at 170 mV. These MOFs are further fabricated into thin films over nickel foam by controlled electrochemical deposition to improve the surface conductivity and the overall stability. The Fe/Ni metal-organic framework film exhibits outstanding electrocatalytic activity with low overpotential of 270 mV at 10 mA cm-2, small Tafel slope, high Faradaic efficiency, high turnover frequency, and great stability.",

keywords = "binder-free film, electrocatalysis, electrochemical deposition, metal-organic frameworks, oxygen evolution reaction",

author = "Lu Wang and Yizhen Wu and Rui Cao and Lantian Ren and Mingxing Chen and Xiao Feng and Junwen Zhou and Bo Wang",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = jul,

day = "6",

doi = "10.1021/acsami.6b05375",

language = "English",

volume = "8",

pages = "16736--16743",

journal = "ACS applied materials & interfaces",

issn = "1944-8244",

publisher = "American Chemical Society",

number = "26",

}

TY - JOUR

T1 - Fe/Ni Metal-Organic Frameworks and Their Binder-Free Thin Films for Efficient Oxygen Evolution with Low Overpotential

AU - Wang, Lu

AU - Wu, Yizhen

AU - Cao, Rui

AU - Ren, Lantian

AU - Chen, Mingxing

AU - Feng, Xiao

AU - Zhou, Junwen

AU - Wang, Bo

PY - 2016/7/6

Y1 - 2016/7/6

N2 - Multivariate metal-organic frameworks with active Fe/Ni building blocks that are spatially arranged in an open structure are synthesized and explored for oxygen evolution reaction. The heterogeneity and porosity of this system prove to show synergy effect and give low onset overpotential at 170 mV. These MOFs are further fabricated into thin films over nickel foam by controlled electrochemical deposition to improve the surface conductivity and the overall stability. The Fe/Ni metal-organic framework film exhibits outstanding electrocatalytic activity with low overpotential of 270 mV at 10 mA cm-2, small Tafel slope, high Faradaic efficiency, high turnover frequency, and great stability.

AB - Multivariate metal-organic frameworks with active Fe/Ni building blocks that are spatially arranged in an open structure are synthesized and explored for oxygen evolution reaction. The heterogeneity and porosity of this system prove to show synergy effect and give low onset overpotential at 170 mV. These MOFs are further fabricated into thin films over nickel foam by controlled electrochemical deposition to improve the surface conductivity and the overall stability. The Fe/Ni metal-organic framework film exhibits outstanding electrocatalytic activity with low overpotential of 270 mV at 10 mA cm-2, small Tafel slope, high Faradaic efficiency, high turnover frequency, and great stability.

KW - binder-free film

KW - electrocatalysis

KW - electrochemical deposition

KW - metal-organic frameworks

KW - oxygen evolution reaction

UR - http://www.scopus.com/inward/record.url?scp=84977667711&partnerID=8YFLogxK

U2 - 10.1021/acsami.6b05375

DO - 10.1021/acsami.6b05375

M3 - Article

AN - SCOPUS:84977667711

SN - 1944-8244

VL - 8

SP - 16736

EP - 16743

JO - ACS applied materials & interfaces

JF - ACS applied materials & interfaces

IS - 26

ER -

Fe/Ni Metal-Organic Frameworks and Their Binder-Free Thin Films for Efficient Oxygen Evolution with Low Overpotential

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this