Enthalpies of dissolution of [Mn(SCZ)3] (PA)2 · H2O in DMF

Qin Pei; Li Yang; Tong Lai Zhang; Jian Guo Zhang; Yuan Hua Sun; Feng Lei Shao

Enthalpies of dissolution of [Mn(SCZ)₃] (PA)₂ · H₂O in DMF

Qin Pei^*, Li Yang, Tong Lai Zhang, Jian Guo Zhang, Yuan Hua Sun, Feng Lei Shao

^*Corresponding author for this work

School of Mechatronical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The molar enthalpies of dissolution of [Mn(SCZ)₃] (PA)₂ · H₂O in N, N-dimethylformamide (DMF) at 298.15 K were measured by means of a SETARAM C80 n calorimeter. The standard molar enthalpy of dissolution was determined to be Δ_dissH_m^θ = -43.607 kJ · mol^-1. The empirical formulae for calculating the enthalpies of dissolution (Δ_dissH = -43.607 - 454.986 + 9378.2b^1/2) of the title coordination complex at different concentrations b (mol · kg^-1) was obtained. Relative apparent molar enthalpy (ΦL_i), relative partial molar enthalpy (L_i) and enthalpy of dilution (Δ_dilH_1,2) were obtained respectively from the experimental data of the enthalpies of dissolution of the coordination compound: ΦL_i = -454.986 + 9378.2b^1/2, L_i = -909.96b + 14067.3b^1/2 and Δ_dilH_1,2 = -454.98(b₂^1/2 - b₁^1/2) + 9378.2(b₂ - b₁).

Original language	English
Pages (from-to)	188-190
Number of pages	3
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	14
Issue number	3
Publication status	Published - Jun 2006

Keywords

Coordination complex
Enthalpy of dissolution
Microcalorimetry
Physical chemistry
[Mn(SCZ)] (PA) · HO

Cite this

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title = "Enthalpies of dissolution of [Mn(SCZ)3] (PA)2 · H2O in DMF",

abstract = "The molar enthalpies of dissolution of [Mn(SCZ)3] (PA)2 · H2O in N, N-dimethylformamide (DMF) at 298.15 K were measured by means of a SETARAM C80 n calorimeter. The standard molar enthalpy of dissolution was determined to be ΔdissHmθ = -43.607 kJ · mol-1. The empirical formulae for calculating the enthalpies of dissolution (ΔdissH = -43.607 - 454.986 + 9378.2b1/2) of the title coordination complex at different concentrations b (mol · kg-1) was obtained. Relative apparent molar enthalpy (ΦLi), relative partial molar enthalpy (Li) and enthalpy of dilution (ΔdilH1,2) were obtained respectively from the experimental data of the enthalpies of dissolution of the coordination compound: ΦLi = -454.986 + 9378.2b1/2, Li = -909.96b + 14067.3b1/2 and ΔdilH1,2 = -454.98(b21/2 - b11/2) + 9378.2(b2 - b1).",

keywords = "Coordination complex, Enthalpy of dissolution, Microcalorimetry, Physical chemistry, [Mn(SCZ)] (PA) · HO",

author = "Qin Pei and Li Yang and Zhang, {Tong Lai} and Zhang, {Jian Guo} and Sun, {Yuan Hua} and Shao, {Feng Lei}",

year = "2006",

month = jun,

language = "English",

volume = "14",

pages = "188--190",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Institute of Chemical Materials, China Academy of Engineering Physics",

number = "3",

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TY - JOUR

T1 - Enthalpies of dissolution of [Mn(SCZ)3] (PA)2 · H2O in DMF

AU - Pei, Qin

AU - Yang, Li

AU - Zhang, Tong Lai

AU - Zhang, Jian Guo

AU - Sun, Yuan Hua

AU - Shao, Feng Lei

PY - 2006/6

Y1 - 2006/6

N2 - The molar enthalpies of dissolution of [Mn(SCZ)3] (PA)2 · H2O in N, N-dimethylformamide (DMF) at 298.15 K were measured by means of a SETARAM C80 n calorimeter. The standard molar enthalpy of dissolution was determined to be ΔdissHmθ = -43.607 kJ · mol-1. The empirical formulae for calculating the enthalpies of dissolution (ΔdissH = -43.607 - 454.986 + 9378.2b1/2) of the title coordination complex at different concentrations b (mol · kg-1) was obtained. Relative apparent molar enthalpy (ΦLi), relative partial molar enthalpy (Li) and enthalpy of dilution (ΔdilH1,2) were obtained respectively from the experimental data of the enthalpies of dissolution of the coordination compound: ΦLi = -454.986 + 9378.2b1/2, Li = -909.96b + 14067.3b1/2 and ΔdilH1,2 = -454.98(b21/2 - b11/2) + 9378.2(b2 - b1).

AB - The molar enthalpies of dissolution of [Mn(SCZ)3] (PA)2 · H2O in N, N-dimethylformamide (DMF) at 298.15 K were measured by means of a SETARAM C80 n calorimeter. The standard molar enthalpy of dissolution was determined to be ΔdissHmθ = -43.607 kJ · mol-1. The empirical formulae for calculating the enthalpies of dissolution (ΔdissH = -43.607 - 454.986 + 9378.2b1/2) of the title coordination complex at different concentrations b (mol · kg-1) was obtained. Relative apparent molar enthalpy (ΦLi), relative partial molar enthalpy (Li) and enthalpy of dilution (ΔdilH1,2) were obtained respectively from the experimental data of the enthalpies of dissolution of the coordination compound: ΦLi = -454.986 + 9378.2b1/2, Li = -909.96b + 14067.3b1/2 and ΔdilH1,2 = -454.98(b21/2 - b11/2) + 9378.2(b2 - b1).

KW - Coordination complex

KW - Enthalpy of dissolution

KW - Microcalorimetry

KW - Physical chemistry

KW - [Mn(SCZ)] (PA) · HO

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M3 - Article

AN - SCOPUS:33746579950

SN - 1006-9941

VL - 14

SP - 188

EP - 190

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 3

ER -

Enthalpies of dissolution of [Mn(SCZ)₃] (PA)₂ · H₂O in DMF

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