Effects of In/Ce to Sn-3.5Ag lead-free solder on microstructures and properties

Enjia Chen*, Xiuchen Zhao, Ying Liu, Dongmei Li, Jingwei Cheng, Hong Li

*Corresponding author for this work

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

3 Citations (Scopus)

Abstract

The Sn-3.5Ag based lead-free electronic solder doped with element In /Ce were prepared respectively using a smelting method with protection by molten salt (SMPMS). The effects of In addition and Ce addition on microstructure, melting point and wettability of Sn-3.5Ag solder were investigated comparatively. And the effects of addition on the intermetallic compound (IMC) layer formed at solder/Cu substrate interface and the shear strength of solder joint were also studied. The results showed that appropriate In or Ce addition can refine Ag3Sn grains and improve the shear strength of solder joint. Element In can significantly reduce the melting point, narrow the melting range of the solder alloy and improve wettability on Cu substrate. When the content of In was 3%, the spreading area was the largest and the wettability was the best. The addition of Ce can efficiently reduce the thickness of the IMC layer grown at the solder/Cu substrate interface and improve the shear strength of solder joint. When the content of Ce was 0.5%, the solder joint had the minimum average IMC thickness and the maximum shear strength.

Original languageEnglish
Title of host publicationMaterials Performance, Modeling and Simulation
PublisherTrans Tech Publications Ltd.
Pages198-204
Number of pages7
ISBN (Print)9783037856093
DOIs
Publication statusPublished - 2013
EventChinese Materials Congress 2012, CMC 2012 - Taiyuan, China
Duration: 13 Jul 201218 Jul 2012

Publication series

NameMaterials Science Forum
Volume749
ISSN (Print)0255-5476
ISSN (Electronic)1662-9752

Conference

ConferenceChinese Materials Congress 2012, CMC 2012
Country/TerritoryChina
CityTaiyuan
Period13/07/1218/07/12

Keywords

  • Lead-free solder
  • Rare earth element
  • Sn-Ag based solder

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