Effect of hexafluorophosphate and conjugated fluoride on the combustion of aluminum powder

Lichen Zhang; Shuo Wang; Lixiang Zhu; Xiaodong Li; Meishuai Zou; Xing Su

doi:10.1088/1742-6596/2478/3/032053

Effect of hexafluorophosphate and conjugated fluoride on the combustion of aluminum powder

Lichen Zhang, Shuo Wang, Lixiang Zhu, Xiaodong Li, Meishuai Zou, Xing Su^*

^*Corresponding author for this work

School of Material Science and Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Conference article › peer-review

Abstract

In this study, the alumina layer on the surface of aluminum powder was removed with hydrofluoric acid. 2-Azido-1,3-dimethylimidazolinium Hexafluorophosphate (ADMHFP) and 4-azido-2,3,5,6-tetrafluorobenzoic acid (ATFBA) were coated on the surface of aluminum to form Al@ADMHFP and Al@ATFBA. Scanning electron microscope and FTIR test results proved that the ADMHFP and ATFBA were coated on aluminum powder. The Al@ADMHFP and Al@ATFBA showed better thermal reaction and combustion performance. The exothermic enthalpy of Al@ADMHFP and Al@ATFBA were increased by about 1.6 times and 1.0 time, with lower ignition temperature and longer burning duration, compared with raw aluminum powder.

Original language	English
Article number	032053
Journal	Journal of Physics: Conference Series
Volume	2478
Issue number	3
DOIs	https://doi.org/10.1088/1742-6596/2478/3/032053
Publication status	Published - 2023
Event	3rd International Conference on Defence Technology, ICDT 2022 - Changsha, China Duration: 22 Aug 2022 → 26 Aug 2022

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title = "Effect of hexafluorophosphate and conjugated fluoride on the combustion of aluminum powder",

abstract = "In this study, the alumina layer on the surface of aluminum powder was removed with hydrofluoric acid. 2-Azido-1,3-dimethylimidazolinium Hexafluorophosphate (ADMHFP) and 4-azido-2,3,5,6-tetrafluorobenzoic acid (ATFBA) were coated on the surface of aluminum to form Al@ADMHFP and Al@ATFBA. Scanning electron microscope and FTIR test results proved that the ADMHFP and ATFBA were coated on aluminum powder. The Al@ADMHFP and Al@ATFBA showed better thermal reaction and combustion performance. The exothermic enthalpy of Al@ADMHFP and Al@ATFBA were increased by about 1.6 times and 1.0 time, with lower ignition temperature and longer burning duration, compared with raw aluminum powder.",

author = "Lichen Zhang and Shuo Wang and Lixiang Zhu and Xiaodong Li and Meishuai Zou and Xing Su",

note = "Publisher Copyright: {\textcopyright} Published under licence by IOP Publishing Ltd.; 3rd International Conference on Defence Technology, ICDT 2022 ; Conference date: 22-08-2022 Through 26-08-2022",

year = "2023",

doi = "10.1088/1742-6596/2478/3/032053",

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TY - JOUR

T1 - Effect of hexafluorophosphate and conjugated fluoride on the combustion of aluminum powder

AU - Zhang, Lichen

AU - Wang, Shuo

AU - Zhu, Lixiang

AU - Li, Xiaodong

AU - Zou, Meishuai

AU - Su, Xing

N1 - Publisher Copyright: © Published under licence by IOP Publishing Ltd.

PY - 2023

Y1 - 2023

N2 - In this study, the alumina layer on the surface of aluminum powder was removed with hydrofluoric acid. 2-Azido-1,3-dimethylimidazolinium Hexafluorophosphate (ADMHFP) and 4-azido-2,3,5,6-tetrafluorobenzoic acid (ATFBA) were coated on the surface of aluminum to form Al@ADMHFP and Al@ATFBA. Scanning electron microscope and FTIR test results proved that the ADMHFP and ATFBA were coated on aluminum powder. The Al@ADMHFP and Al@ATFBA showed better thermal reaction and combustion performance. The exothermic enthalpy of Al@ADMHFP and Al@ATFBA were increased by about 1.6 times and 1.0 time, with lower ignition temperature and longer burning duration, compared with raw aluminum powder.

AB - In this study, the alumina layer on the surface of aluminum powder was removed with hydrofluoric acid. 2-Azido-1,3-dimethylimidazolinium Hexafluorophosphate (ADMHFP) and 4-azido-2,3,5,6-tetrafluorobenzoic acid (ATFBA) were coated on the surface of aluminum to form Al@ADMHFP and Al@ATFBA. Scanning electron microscope and FTIR test results proved that the ADMHFP and ATFBA were coated on aluminum powder. The Al@ADMHFP and Al@ATFBA showed better thermal reaction and combustion performance. The exothermic enthalpy of Al@ADMHFP and Al@ATFBA were increased by about 1.6 times and 1.0 time, with lower ignition temperature and longer burning duration, compared with raw aluminum powder.

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U2 - 10.1088/1742-6596/2478/3/032053

DO - 10.1088/1742-6596/2478/3/032053

M3 - Conference article

AN - SCOPUS:85167452213

SN - 1742-6588

VL - 2478

JO - Journal of Physics: Conference Series

JF - Journal of Physics: Conference Series

IS - 3

M1 - 032053

T2 - 3rd International Conference on Defence Technology, ICDT 2022

Y2 - 22 August 2022 through 26 August 2022

ER -

Effect of hexafluorophosphate and conjugated fluoride on the combustion of aluminum powder

Abstract

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