Cubic polyoxometalate-organic molecular cage

Shou Tian Zheng; Jie Zhang; Xin Xiong Li; Wei Hui Fang; Guo Yu Yang

doi:10.1021/ja105986b

Cubic polyoxometalate-organic molecular cage

Shou Tian Zheng, Jie Zhang, Xin Xiong Li, Wei Hui Fang, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

365 Citations (Scopus)

Abstract

Tris(hydroxymethyl)aminomethane (Tris) was successfully grafted onto the surface of a Ni₆-substituted polyoxotungstate formed in situ to further generate a three-connected polyoxometalate building block. The cooperative assembly of Tris functionalized three-connected building blocks and rigid 1,3,5-benzenetricarboxylate gave rise to an unprecedented cubic polyoxometalate-organic molecular cage with high thermal and hydrothermal stability.

Original language	English
Pages (from-to)	15102-15103
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	132
Issue number	43
DOIs	https://doi.org/10.1021/ja105986b
Publication status	Published - 3 Nov 2010

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10.1021/ja105986b

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title = "Cubic polyoxometalate-organic molecular cage",

abstract = "Tris(hydroxymethyl)aminomethane (Tris) was successfully grafted onto the surface of a Ni6-substituted polyoxotungstate formed in situ to further generate a three-connected polyoxometalate building block. The cooperative assembly of Tris functionalized three-connected building blocks and rigid 1,3,5-benzenetricarboxylate gave rise to an unprecedented cubic polyoxometalate-organic molecular cage with high thermal and hydrothermal stability.",

author = "Zheng, {Shou Tian} and Jie Zhang and Li, {Xin Xiong} and Fang, {Wei Hui} and Yang, {Guo Yu}",

year = "2010",

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AU - Zheng, Shou Tian

AU - Zhang, Jie

AU - Li, Xin Xiong

AU - Fang, Wei Hui

AU - Yang, Guo Yu

PY - 2010/11/3

Y1 - 2010/11/3

N2 - Tris(hydroxymethyl)aminomethane (Tris) was successfully grafted onto the surface of a Ni6-substituted polyoxotungstate formed in situ to further generate a three-connected polyoxometalate building block. The cooperative assembly of Tris functionalized three-connected building blocks and rigid 1,3,5-benzenetricarboxylate gave rise to an unprecedented cubic polyoxometalate-organic molecular cage with high thermal and hydrothermal stability.

AB - Tris(hydroxymethyl)aminomethane (Tris) was successfully grafted onto the surface of a Ni6-substituted polyoxotungstate formed in situ to further generate a three-connected polyoxometalate building block. The cooperative assembly of Tris functionalized three-connected building blocks and rigid 1,3,5-benzenetricarboxylate gave rise to an unprecedented cubic polyoxometalate-organic molecular cage with high thermal and hydrothermal stability.

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U2 - 10.1021/ja105986b

DO - 10.1021/ja105986b

M3 - Article

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VL - 132

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 43

ER -

Cubic polyoxometalate-organic molecular cage

Abstract

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