TY - JOUR
T1 - Creation of Assembled Plasmonic Network Architectures with Selective Capture of Guest Molecules in Hotspots Region
AU - Sun, Fuwei
AU - Tian, Li
AU - He, Guokang
AU - Gao, Ning
AU - Zhao, Hongwei
AU - Liu, Weigang
AU - Liu, Chao
AU - An, Qi
AU - Wang, Chen
AU - Li, Guangtao
N1 - Publisher Copyright:
© 2023 Wiley-VCH GmbH.
PY - 2023/3/17
Y1 - 2023/3/17
N2 - Plasmonic networks attract increasing attention owing to their strong plasmon coupling effects at hotspot regions, where intriguing, collective optical behavior and field enhancement occur. Engineering network architectures with flexible control over density and intensity of hotspots, thus fine-tuning electromagnetic field is the prerequisite for fully exploiting their potential use in diverse plasmon-based applications, but it represents a great challenge. Herein, a cage-assisted bottom-up self-assembly strategy is proposed to construct a series of cage-bridged complex network architectures with a high degree of flexibility in hotspot modulation. Critical parameters associated with plasmonic networks, including interparticle distance, the density and intensity of hotspots, as well as molecule accessibility of hotspot can be simultaneously and flexibly adjusted at will. Importantly, the integration of host–guest chemistry of molecular cages into interparticle regions of networks endows selective molecule trapping capability in hotspots, offering tremendous opportunities for broader plasmon-based applications. The present study not only develops efficient plasmonic networks with enhanced density of hotspots and intense electromagnetic fields, but also provides new avenues for artificially engineering network architectures with advanced functionalities and facilitates further applications in sensing and optoelectronics.
AB - Plasmonic networks attract increasing attention owing to their strong plasmon coupling effects at hotspot regions, where intriguing, collective optical behavior and field enhancement occur. Engineering network architectures with flexible control over density and intensity of hotspots, thus fine-tuning electromagnetic field is the prerequisite for fully exploiting their potential use in diverse plasmon-based applications, but it represents a great challenge. Herein, a cage-assisted bottom-up self-assembly strategy is proposed to construct a series of cage-bridged complex network architectures with a high degree of flexibility in hotspot modulation. Critical parameters associated with plasmonic networks, including interparticle distance, the density and intensity of hotspots, as well as molecule accessibility of hotspot can be simultaneously and flexibly adjusted at will. Importantly, the integration of host–guest chemistry of molecular cages into interparticle regions of networks endows selective molecule trapping capability in hotspots, offering tremendous opportunities for broader plasmon-based applications. The present study not only develops efficient plasmonic networks with enhanced density of hotspots and intense electromagnetic fields, but also provides new avenues for artificially engineering network architectures with advanced functionalities and facilitates further applications in sensing and optoelectronics.
KW - host–guest chemistry
KW - hotspots modulation
KW - molecular cages
KW - network architectures
KW - plasmonic nanoparticles
UR - http://www.scopus.com/inward/record.url?scp=85147024383&partnerID=8YFLogxK
U2 - 10.1002/adom.202201911
DO - 10.1002/adom.202201911
M3 - Article
AN - SCOPUS:85147024383
SN - 2195-1071
VL - 11
JO - Advanced Optical Materials
JF - Advanced Optical Materials
IS - 6
M1 - 2201911
ER -