Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of [{FeIIFeIII12(μ3-OH) 12(μ4-PO4)4}(B-α-PW 9O34)4]22-

Jun Wei Zhao; Jie Zhang; Shou Tian Zheng; Guo Yu Yang

doi:10.1021/ic701810t

Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of [{Fe^IIFe^III₁₂(μ₃-OH) ₁₂(μ₄-PO₄)₄}(B-α-PW ₉O₃₄)₄]^22-

Jun Wei Zhao, Jie Zhang, Shou Tian Zheng, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

89 Citations (Scopus)

Abstract

A novel tetrameric cluster, (enH₂)_3.5H ₁₅[{Fe^IIFe^III₁₂(μ₃-OH) ₁₂(μ₄-PO₄)₄}(B-α-PW ₉O₃₄)₄]·83H₂O (1; en = ethylenediamine), has been hydrothermally synthesized and characterized by IR, optical diffuse reflectance, thermogravimetric analysis, and single-crystal X-ray diffraction. The skeleton of 1 is composed of four tri-Fe ^III-substituted [Fe^III₃(μ₃-OH) ₃(B-α-PW₉O₃₄)]^3- Keggin moieties fused together through a Fe^II₂O₂ unit and four μ₄-PO₄ bridges, resulting in a unique tetramer with C₂ symmetry. Magnetic measurements indicate that 1 reveals the antiferromagnetic interactions between Fe^II and Fe^III centers.

Original language	English
Pages (from-to)	10944-10946
Number of pages	3
Journal	Inorganic Chemistry
Volume	46
Issue number	26
DOIs	https://doi.org/10.1021/ic701810t
Publication status	Published - 24 Dec 2007
Externally published	Yes

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@article{5fe02dc7bc494b1cb2f01f95ecb820fc,

title = "Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of [{FeIIFeIII12(μ3-OH) 12(μ4-PO4)4}(B-α-PW 9O34)4]22-",

abstract = "A novel tetrameric cluster, (enH2)3.5H 15[{FeIIFeIII12(μ3-OH) 12(μ4-PO4)4}(B-α-PW 9O34)4]·83H2O (1; en = ethylenediamine), has been hydrothermally synthesized and characterized by IR, optical diffuse reflectance, thermogravimetric analysis, and single-crystal X-ray diffraction. The skeleton of 1 is composed of four tri-Fe III-substituted [FeIII3(μ3-OH) 3(B-α-PW9O34)]3- Keggin moieties fused together through a FeII2O2 unit and four μ4-PO4 bridges, resulting in a unique tetramer with C2 symmetry. Magnetic measurements indicate that 1 reveals the antiferromagnetic interactions between FeII and FeIII centers.",

author = "Zhao, {Jun Wei} and Jie Zhang and Zheng, {Shou Tian} and Yang, {Guo Yu}",

year = "2007",

month = dec,

day = "24",

doi = "10.1021/ic701810t",

language = "English",

volume = "46",

pages = "10944--10946",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "26",

}

Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of [{Fe^IIFe^III₁₂(μ₃-OH) ₁₂(μ₄-PO₄)₄}(B-α-PW ₉O₃₄)₄]^22-. / Zhao, Jun Wei; Zhang, Jie; Zheng, Shou Tian et al.
In: Inorganic Chemistry, Vol. 46, No. 26, 24.12.2007, p. 10944-10946.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of [{FeIIFeIII12(μ3-OH) 12(μ4-PO4)4}(B-α-PW 9O34)4]22-

AU - Zhao, Jun Wei

AU - Zhang, Jie

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2007/12/24

Y1 - 2007/12/24

N2 - A novel tetrameric cluster, (enH2)3.5H 15[{FeIIFeIII12(μ3-OH) 12(μ4-PO4)4}(B-α-PW 9O34)4]·83H2O (1; en = ethylenediamine), has been hydrothermally synthesized and characterized by IR, optical diffuse reflectance, thermogravimetric analysis, and single-crystal X-ray diffraction. The skeleton of 1 is composed of four tri-Fe III-substituted [FeIII3(μ3-OH) 3(B-α-PW9O34)]3- Keggin moieties fused together through a FeII2O2 unit and four μ4-PO4 bridges, resulting in a unique tetramer with C2 symmetry. Magnetic measurements indicate that 1 reveals the antiferromagnetic interactions between FeII and FeIII centers.

AB - A novel tetrameric cluster, (enH2)3.5H 15[{FeIIFeIII12(μ3-OH) 12(μ4-PO4)4}(B-α-PW 9O34)4]·83H2O (1; en = ethylenediamine), has been hydrothermally synthesized and characterized by IR, optical diffuse reflectance, thermogravimetric analysis, and single-crystal X-ray diffraction. The skeleton of 1 is composed of four tri-Fe III-substituted [FeIII3(μ3-OH) 3(B-α-PW9O34)]3- Keggin moieties fused together through a FeII2O2 unit and four μ4-PO4 bridges, resulting in a unique tetramer with C2 symmetry. Magnetic measurements indicate that 1 reveals the antiferromagnetic interactions between FeII and FeIII centers.

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VL - 46

SP - 10944

EP - 10946

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 26

ER -

Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of [{Fe^IIFe^III₁₂(μ₃-OH) ₁₂(μ₄-PO₄)₄}(B-α-PW ₉O₃₄)₄]^22-

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