Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: First (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel {Cu8} cluster

Jun Wei Zhao; Jie Zhang; Shou Tian Zheng; Guo Yu Yang

doi:10.1039/b713510f

Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: First (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel {Cu₈} cluster

Jun Wei Zhao, Jie Zhang, Shou Tian Zheng, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

30 Citations (Scopus)

Abstract

An unprecedented (3,6)-connected 3-D framework constructed from sandwich-type polyoxometalate building blocks containing a {Cu₈} cluster, [Cu(H₂O)₂]H₂[Cu₈(dap) ₄(H₂O)₂(α-B-GeW₉O ₃₄)₂] (dap = 1,2-diaminopropane) has been hydrothermally made, which provides a novel topological structure in transition metal substituted polyoxometalates.

Original language	English
Pages (from-to)	570-572
Number of pages	3
Journal	Chemical Communications
Volume	8
Issue number	5
DOIs	https://doi.org/10.1039/b713510f
Publication status	Published - 2008
Externally published	Yes

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Zhao, J. W., Zhang, J., Zheng, S. T., & Yang, G. Y. (2008). Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: First (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel {Cu₈} cluster. Chemical Communications, 8(5), 570-572. https://doi.org/10.1039/b713510f

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title = "Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: First (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel {Cu8} cluster",

abstract = "An unprecedented (3,6)-connected 3-D framework constructed from sandwich-type polyoxometalate building blocks containing a {Cu8} cluster, [Cu(H2O)2]H2[Cu8(dap) 4(H2O)2(α-B-GeW9O 34)2] (dap = 1,2-diaminopropane) has been hydrothermally made, which provides a novel topological structure in transition metal substituted polyoxometalates.",

author = "Zhao, {Jun Wei} and Jie Zhang and Zheng, {Shou Tian} and Yang, {Guo Yu}",

year = "2008",

doi = "10.1039/b713510f",

language = "English",

volume = "8",

pages = "570--572",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

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}

Zhao, JW, Zhang, J, Zheng, ST & Yang, GY 2008, 'Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: First (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel {Cu₈} cluster', Chemical Communications, vol. 8, no. 5, pp. 570-572. https://doi.org/10.1039/b713510f

Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: First (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel {Cu₈} cluster. / Zhao, Jun Wei; Zhang, Jie; Zheng, Shou Tian et al.
In: Chemical Communications, Vol. 8, No. 5, 2008, p. 570-572.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions

T2 - First (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel {Cu8} cluster

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PY - 2008

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AB - An unprecedented (3,6)-connected 3-D framework constructed from sandwich-type polyoxometalate building blocks containing a {Cu8} cluster, [Cu(H2O)2]H2[Cu8(dap) 4(H2O)2(α-B-GeW9O 34)2] (dap = 1,2-diaminopropane) has been hydrothermally made, which provides a novel topological structure in transition metal substituted polyoxometalates.

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