Cation-induced synthesis of new polyoxopalladates

Zheng Guo Lin; Bo Wang; Jie Cao; Bao Kuan Chen; Yuan Zhe Gao; Ying Nan Chi; Chong Xu; Xian Qiang Huang; Ruo Dan Han; Shuang Yue Su; Chang Wen Hu

doi:10.1021/ic300428g

Cation-induced synthesis of new polyoxopalladates

Zheng Guo Lin, Bo Wang^*, Jie Cao, Bao Kuan Chen, Yuan Zhe Gao, Ying Nan Chi, Chong Xu, Xian Qiang Huang, Ruo Dan Han, Shuang Yue Su, Chang Wen Hu

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

40 Citations (Scopus)

Abstract

Seven polyoxopalladate compounds, [Pd ₁₅(SeO ₃) ₁₀(μ ₃-O) ₁₀] ^10-, with Na ⁺ (1) and K ⁺ (2) as counterions, and Na ₆[M ^II{Pd ₁₂(SeO ₃) ₈(μ ₄-O) ₈}]̇nH ₂O (M = Co (3), Zn (4), Ni (5), Cu (6), Mn (7); n = 7-9), have been prepared and characterized by SXRD, FT-IR, UV-vis, EA, TGA, and ESI-MS. These compounds comprise two distinct cluster configurations, {Pd ₁₅} and {M ^IIPd ₁₂}, which reveals the possibility of obtaining desired noble metal clusters with a certain nuclearity by using different cations as potential structural directing or template agents in synthesis. All compounds showed apparent absorptions in the visible light region, while 3 and 7 were found to show paramagnetic behavior typical of mononuclear Co ^II and Mn ^II complexes with zero-field splitting.

Original language	English
Pages (from-to)	4435-4437
Number of pages	3
Journal	Inorganic Chemistry
Volume	51
Issue number	8
DOIs	https://doi.org/10.1021/ic300428g
Publication status	Published - 16 Apr 2012

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title = "Cation-induced synthesis of new polyoxopalladates",

abstract = "Seven polyoxopalladate compounds, [Pd 15(SeO 3) 10(μ 3-O) 10] 10-, with Na + (1) and K + (2) as counterions, and Na 6[M II{Pd 12(SeO 3) 8(μ 4-O) 8}{\.]}nH 2O (M = Co (3), Zn (4), Ni (5), Cu (6), Mn (7); n = 7-9), have been prepared and characterized by SXRD, FT-IR, UV-vis, EA, TGA, and ESI-MS. These compounds comprise two distinct cluster configurations, {Pd 15} and {M IIPd 12}, which reveals the possibility of obtaining desired noble metal clusters with a certain nuclearity by using different cations as potential structural directing or template agents in synthesis. All compounds showed apparent absorptions in the visible light region, while 3 and 7 were found to show paramagnetic behavior typical of mononuclear Co II and Mn II complexes with zero-field splitting.",

author = "Lin, {Zheng Guo} and Bo Wang and Jie Cao and Chen, {Bao Kuan} and Gao, {Yuan Zhe} and Chi, {Ying Nan} and Chong Xu and Huang, {Xian Qiang} and Han, {Ruo Dan} and Su, {Shuang Yue} and Hu, {Chang Wen}",

year = "2012",

month = apr,

day = "16",

doi = "10.1021/ic300428g",

language = "English",

volume = "51",

pages = "4435--4437",

journal = "Inorganic Chemistry",

issn = "0020-1669",

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TY - JOUR

T1 - Cation-induced synthesis of new polyoxopalladates

AU - Lin, Zheng Guo

AU - Wang, Bo

AU - Cao, Jie

AU - Chen, Bao Kuan

AU - Gao, Yuan Zhe

AU - Chi, Ying Nan

AU - Xu, Chong

AU - Huang, Xian Qiang

AU - Han, Ruo Dan

AU - Su, Shuang Yue

AU - Hu, Chang Wen

PY - 2012/4/16

Y1 - 2012/4/16

N2 - Seven polyoxopalladate compounds, [Pd 15(SeO 3) 10(μ 3-O) 10] 10-, with Na + (1) and K + (2) as counterions, and Na 6[M II{Pd 12(SeO 3) 8(μ 4-O) 8}]̇nH 2O (M = Co (3), Zn (4), Ni (5), Cu (6), Mn (7); n = 7-9), have been prepared and characterized by SXRD, FT-IR, UV-vis, EA, TGA, and ESI-MS. These compounds comprise two distinct cluster configurations, {Pd 15} and {M IIPd 12}, which reveals the possibility of obtaining desired noble metal clusters with a certain nuclearity by using different cations as potential structural directing or template agents in synthesis. All compounds showed apparent absorptions in the visible light region, while 3 and 7 were found to show paramagnetic behavior typical of mononuclear Co II and Mn II complexes with zero-field splitting.

AB - Seven polyoxopalladate compounds, [Pd 15(SeO 3) 10(μ 3-O) 10] 10-, with Na + (1) and K + (2) as counterions, and Na 6[M II{Pd 12(SeO 3) 8(μ 4-O) 8}]̇nH 2O (M = Co (3), Zn (4), Ni (5), Cu (6), Mn (7); n = 7-9), have been prepared and characterized by SXRD, FT-IR, UV-vis, EA, TGA, and ESI-MS. These compounds comprise two distinct cluster configurations, {Pd 15} and {M IIPd 12}, which reveals the possibility of obtaining desired noble metal clusters with a certain nuclearity by using different cations as potential structural directing or template agents in synthesis. All compounds showed apparent absorptions in the visible light region, while 3 and 7 were found to show paramagnetic behavior typical of mononuclear Co II and Mn II complexes with zero-field splitting.

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U2 - 10.1021/ic300428g

DO - 10.1021/ic300428g

M3 - Article

AN - SCOPUS:84859786760

SN - 0020-1669

VL - 51

SP - 4435

EP - 4437

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 8

ER -

Cation-induced synthesis of new polyoxopalladates

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