Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate

Wen Zhuo Zhao; Yi Nan Zhang; You Zhao Lan; Jian Wen Cheng; Guo Yu Yang

doi:10.1021/acs.inorgchem.2c00102

Ba₂B₁₀O₁₆(OH)₂·(H₃BO₃)(H₂O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate

Wen Zhuo Zhao, Yi Nan Zhang, You Zhao Lan, Jian Wen Cheng^*, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Zhejiang Normal University

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

A new acentric barium borate, Ba2B10O16(OH)2·(H3BO3)(H2O) (1), was synthesized via a hydrothermal process. Compound 1 contains two different boron oxide units of [B5O10(OH)]6- anions and H3BO3 molecules and features 9-ring channels along the c axis in a layered structure. This barium borate is a possible deep-ultraviolet nonlinear-optical crystal for its moderate second-harmonic-generation signal and wide transparency window below 190 nm.

Original language	English
Pages (from-to)	4246-4250
Number of pages	5
Journal	Inorganic Chemistry
Volume	61
Issue number	10
DOIs	https://doi.org/10.1021/acs.inorgchem.2c00102
Publication status	Published - 14 Mar 2022

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10.1021/acs.inorgchem.2c00102

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title = "Ba2B10O16(OH)2·(H3BO3)(H2O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate",

abstract = "A new acentric barium borate, Ba2B10O16(OH)2·(H3BO3)(H2O) (1), was synthesized via a hydrothermal process. Compound 1 contains two different boron oxide units of [B5O10(OH)]6- anions and H3BO3 molecules and features 9-ring channels along the c axis in a layered structure. This barium borate is a possible deep-ultraviolet nonlinear-optical crystal for its moderate second-harmonic-generation signal and wide transparency window below 190 nm.",

author = "Zhao, {Wen Zhuo} and Zhang, {Yi Nan} and Lan, {You Zhao} and Cheng, {Jian Wen} and Yang, {Guo Yu}",

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AU - Zhao, Wen Zhuo

AU - Zhang, Yi Nan

AU - Lan, You Zhao

AU - Cheng, Jian Wen

AU - Yang, Guo Yu

PY - 2022/3/14

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N2 - A new acentric barium borate, Ba2B10O16(OH)2·(H3BO3)(H2O) (1), was synthesized via a hydrothermal process. Compound 1 contains two different boron oxide units of [B5O10(OH)]6- anions and H3BO3 molecules and features 9-ring channels along the c axis in a layered structure. This barium borate is a possible deep-ultraviolet nonlinear-optical crystal for its moderate second-harmonic-generation signal and wide transparency window below 190 nm.

AB - A new acentric barium borate, Ba2B10O16(OH)2·(H3BO3)(H2O) (1), was synthesized via a hydrothermal process. Compound 1 contains two different boron oxide units of [B5O10(OH)]6- anions and H3BO3 molecules and features 9-ring channels along the c axis in a layered structure. This barium borate is a possible deep-ultraviolet nonlinear-optical crystal for its moderate second-harmonic-generation signal and wide transparency window below 190 nm.

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JO - Inorganic Chemistry

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IS - 10

ER -

Ba₂B₁₀O₁₆(OH)₂·(H₃BO₃)(H₂O): A Possible Deep-Ultraviolet Nonlinear-Optical Barium Borate

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