A novel open-framework zinc phosphite, Zn3(HPO3) 4·Ni(en)2(H2O)2, templated by a transition-metal complex

Zhi En Lin; Jie Zhang; Shou Tian Zheng; Guo Yu Yang

doi:10.1002/ejic.200300601

A novel open-framework zinc phosphite, Zn₃(HPO₃) ₄·Ni(en)₂(H₂O)₂, templated by a transition-metal complex

Zhi En Lin, Jie Zhang, Shou Tian Zheng, Guo Yu Yang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

34 Citations (Scopus)

Abstract

A new three-dimensional zinc phosphite, Zn₃(HPO ₃)₄·Ni(en)₂(H₂O) ₂, which is the first example of an open-framework metal phosphite templated by a transition-metal complex, was hydrothermally synthesized. The connectivity of the strictly alternating ZnO₄ and HPO₃ units results in a three-dimensional framework with intersecting 8-ring and 12-ring channels, in which the transition-metal complexes reside.

Original language	English
Pages (from-to)	953-955
Number of pages	3
Journal	European Journal of Inorganic Chemistry
Issue number	5
DOIs	https://doi.org/10.1002/ejic.200300601
Publication status	Published - 5 Mar 2004
Externally published	Yes

Keywords

Inorganic solid
Nickel
Open framework
Template synthesis
Zinc

Access to Document

10.1002/ejic.200300601

Cite this

@article{267f912dd5e242b790837b5a0f92e2fe,

title = "A novel open-framework zinc phosphite, Zn3(HPO3) 4·Ni(en)2(H2O)2, templated by a transition-metal complex",

abstract = "A new three-dimensional zinc phosphite, Zn3(HPO 3)4·Ni(en)2(H2O) 2, which is the first example of an open-framework metal phosphite templated by a transition-metal complex, was hydrothermally synthesized. The connectivity of the strictly alternating ZnO4 and HPO3 units results in a three-dimensional framework with intersecting 8-ring and 12-ring channels, in which the transition-metal complexes reside.",

keywords = "Inorganic solid, Nickel, Open framework, Template synthesis, Zinc",

author = "Lin, {Zhi En} and Jie Zhang and Zheng, {Shou Tian} and Yang, {Guo Yu}",

year = "2004",

month = mar,

day = "5",

doi = "10.1002/ejic.200300601",

language = "English",

pages = "953--955",

journal = "European Journal of Inorganic Chemistry",

issn = "1434-1948",

publisher = "Wiley-VCH Verlag",

number = "5",

}

TY - JOUR

T1 - A novel open-framework zinc phosphite, Zn3(HPO3) 4·Ni(en)2(H2O)2, templated by a transition-metal complex

AU - Lin, Zhi En

AU - Zhang, Jie

AU - Zheng, Shou Tian

AU - Yang, Guo Yu

PY - 2004/3/5

Y1 - 2004/3/5

N2 - A new three-dimensional zinc phosphite, Zn3(HPO 3)4·Ni(en)2(H2O) 2, which is the first example of an open-framework metal phosphite templated by a transition-metal complex, was hydrothermally synthesized. The connectivity of the strictly alternating ZnO4 and HPO3 units results in a three-dimensional framework with intersecting 8-ring and 12-ring channels, in which the transition-metal complexes reside.

AB - A new three-dimensional zinc phosphite, Zn3(HPO 3)4·Ni(en)2(H2O) 2, which is the first example of an open-framework metal phosphite templated by a transition-metal complex, was hydrothermally synthesized. The connectivity of the strictly alternating ZnO4 and HPO3 units results in a three-dimensional framework with intersecting 8-ring and 12-ring channels, in which the transition-metal complexes reside.

KW - Inorganic solid

KW - Nickel

KW - Open framework

KW - Template synthesis

KW - Zinc

UR - http://www.scopus.com/inward/record.url?scp=4544317261&partnerID=8YFLogxK

U2 - 10.1002/ejic.200300601

DO - 10.1002/ejic.200300601

M3 - Article

AN - SCOPUS:4544317261

SN - 1434-1948

SP - 953

EP - 955

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

IS - 5

ER -

A novel open-framework zinc phosphite, Zn₃(HPO₃) ₄·Ni(en)₂(H₂O)₂, templated by a transition-metal complex

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this