TY - JOUR
T1 - A novel nitrogen-rich cadmium coordination compound based on 1,5-diaminotetrazole
T2 - Synthesis, structure investigation, and thermal properties
AU - Li, Zhi Min
AU - Zhang, Jian Guo
AU - Cui, Yan
AU - Zhang, Tong Lai
AU - Shu, Yuan Jie
AU - Sinditskii, Valery P.
AU - Serushkin, Valery V.
AU - Egorshin, Vyacheslav Yu
PY - 2010/9/9
Y1 - 2010/9/9
N2 - A new coordination compound [Cd(DAT)6](PA)2· (H2O)4 using 1,5-diaminotetrazole (DAT) as a ligand was synthesized and characterized by applying X-ray single crystal diffraction, elemental analysis, and Fourier transform infrared (FT-IR) spectroscopy. The central cadmium(II) cation is coordinated by six N atoms from six DAT molecules to form a six-coordinated and slightly distorted octahedral configuration. The coordination cation is situated between the two picrate (PA) anions whose benzene-ring planes are parallel to each other. All of the molecular units are linked together by intermolecular hydrogen bonds. The thermal decomposition mechanism of the title compound was investigated through differential scanning calorimetry (DSC), thermogravimetric/differential analysis (TG-DTG), and FT-IR analyses. The kinetic parameters of the first exothermic process of this complex were calculated by applying Kissingers and Ozawa-Doyles methods.
AB - A new coordination compound [Cd(DAT)6](PA)2· (H2O)4 using 1,5-diaminotetrazole (DAT) as a ligand was synthesized and characterized by applying X-ray single crystal diffraction, elemental analysis, and Fourier transform infrared (FT-IR) spectroscopy. The central cadmium(II) cation is coordinated by six N atoms from six DAT molecules to form a six-coordinated and slightly distorted octahedral configuration. The coordination cation is situated between the two picrate (PA) anions whose benzene-ring planes are parallel to each other. All of the molecular units are linked together by intermolecular hydrogen bonds. The thermal decomposition mechanism of the title compound was investigated through differential scanning calorimetry (DSC), thermogravimetric/differential analysis (TG-DTG), and FT-IR analyses. The kinetic parameters of the first exothermic process of this complex were calculated by applying Kissingers and Ozawa-Doyles methods.
UR - http://www.scopus.com/inward/record.url?scp=77956507593&partnerID=8YFLogxK
U2 - 10.1021/je100001b
DO - 10.1021/je100001b
M3 - Article
AN - SCOPUS:77956507593
SN - 0021-9568
VL - 55
SP - 3109
EP - 3116
JO - Journal of Chemical and Engineering Data
JF - Journal of Chemical and Engineering Data
IS - 9
ER -