A new mixed metal borate of BaPb[B5O9(OH)] ·H2O with acentric structure

Han Qing Wu; Huan He; Bai Fei Yang; Guo Yu Yang

doi:10.1016/j.inoche.2013.09.027

A new mixed metal borate of BaPb[B₅O₉(OH)] ·H₂O with acentric structure

Han Qing Wu, Huan He, Bai Fei Yang, Guo Yu Yang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

A new mixed matel borate, BaPb[B₅O₉(OH)] ·H₂O (1), with an acentric structure has been successfully made under hydrothermal conditions. A single-crystal X-ray structural analysis shows that 1 crystallizes in the monoclinic space group Cc (No. 9) with a = 11.3194(6) Å, b = 6.6265(3) Å, c = 12.9256(8) Å, β = 115.065(7), and Z = 4. Compound 1 has a layered structure with 9-membered ring (MR) windows, where the Pb^{2 +} cations locate, while the Ba ^{2 +} cations site in the channels formed by H-bonding interactions of adjacent layers. Second-harmonic generation (SHG) measurements on the powder samples reveal that 1 exhibits SHG efficiency approximately 2.2 times that of KH₂PO₄ (KDP) and phase-matching. Also it has a UV cutoff edge below 200 nm.

Original language	English
Pages (from-to)	77-79
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	37
DOIs	https://doi.org/10.1016/j.inoche.2013.09.027
Publication status	Published - 2013

Keywords

Borate
Cluster
Crystal structure
Hydrothermal syntheses
Nonlinear optical

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10.1016/j.inoche.2013.09.027

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title = "A new mixed metal borate of BaPb[B5O9(OH)] ·H2O with acentric structure",

abstract = "A new mixed matel borate, BaPb[B5O9(OH)] ·H2O (1), with an acentric structure has been successfully made under hydrothermal conditions. A single-crystal X-ray structural analysis shows that 1 crystallizes in the monoclinic space group Cc (No. 9) with a = 11.3194(6) {\AA}, b = 6.6265(3) {\AA}, c = 12.9256(8) {\AA}, β = 115.065(7), and Z = 4. Compound 1 has a layered structure with 9-membered ring (MR) windows, where the Pb2 + cations locate, while the Ba 2 + cations site in the channels formed by H-bonding interactions of adjacent layers. Second-harmonic generation (SHG) measurements on the powder samples reveal that 1 exhibits SHG efficiency approximately 2.2 times that of KH2PO4 (KDP) and phase-matching. Also it has a UV cutoff edge below 200 nm.",

keywords = "Borate, Cluster, Crystal structure, Hydrothermal syntheses, Nonlinear optical",

author = "Wu, {Han Qing} and Huan He and Yang, {Bai Fei} and Yang, {Guo Yu}",

year = "2013",

doi = "10.1016/j.inoche.2013.09.027",

language = "English",

volume = "37",

pages = "77--79",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

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T1 - A new mixed metal borate of BaPb[B5O9(OH)] ·H2O with acentric structure

AU - Wu, Han Qing

AU - He, Huan

AU - Yang, Bai Fei

AU - Yang, Guo Yu

PY - 2013

Y1 - 2013

N2 - A new mixed matel borate, BaPb[B5O9(OH)] ·H2O (1), with an acentric structure has been successfully made under hydrothermal conditions. A single-crystal X-ray structural analysis shows that 1 crystallizes in the monoclinic space group Cc (No. 9) with a = 11.3194(6) Å, b = 6.6265(3) Å, c = 12.9256(8) Å, β = 115.065(7), and Z = 4. Compound 1 has a layered structure with 9-membered ring (MR) windows, where the Pb2 + cations locate, while the Ba 2 + cations site in the channels formed by H-bonding interactions of adjacent layers. Second-harmonic generation (SHG) measurements on the powder samples reveal that 1 exhibits SHG efficiency approximately 2.2 times that of KH2PO4 (KDP) and phase-matching. Also it has a UV cutoff edge below 200 nm.

AB - A new mixed matel borate, BaPb[B5O9(OH)] ·H2O (1), with an acentric structure has been successfully made under hydrothermal conditions. A single-crystal X-ray structural analysis shows that 1 crystallizes in the monoclinic space group Cc (No. 9) with a = 11.3194(6) Å, b = 6.6265(3) Å, c = 12.9256(8) Å, β = 115.065(7), and Z = 4. Compound 1 has a layered structure with 9-membered ring (MR) windows, where the Pb2 + cations locate, while the Ba 2 + cations site in the channels formed by H-bonding interactions of adjacent layers. Second-harmonic generation (SHG) measurements on the powder samples reveal that 1 exhibits SHG efficiency approximately 2.2 times that of KH2PO4 (KDP) and phase-matching. Also it has a UV cutoff edge below 200 nm.

KW - Borate

KW - Cluster

KW - Crystal structure

KW - Hydrothermal syntheses

KW - Nonlinear optical

UR - http://www.scopus.com/inward/record.url?scp=84885333966&partnerID=8YFLogxK

U2 - 10.1016/j.inoche.2013.09.027

DO - 10.1016/j.inoche.2013.09.027

M3 - Article

AN - SCOPUS:84885333966

SN - 1387-7003

VL - 37

SP - 77

EP - 79

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

A new mixed metal borate of BaPb[B₅O₉(OH)] ·H₂O with acentric structure

Abstract

Keywords

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