2D flexible metal–organic frameworks with [Cd2(μ2-X)2](X = Cl or Br) units exhibiting selective fluorescence sensing for small molecules

Xu Hui Jin; Jian Ke Sun; Li Xuan Cai; Jie Zhang

doi:10.1039/c0cc04084c

2D flexible metal–organic frameworks with [Cd₂(μ₂-X)₂](X = Cl or Br) units exhibiting selective fluorescence sensing for small molecules

Xu Hui Jin, Jian Ke Sun, Li Xuan Cai, Jie Zhang^*

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

83 Citations (Scopus)

Abstract

Two isomorphous 2D flexible metal–organic frameworks with [Cd₂(μ₂-X)₂] (X = Cl or Br) units and dynamic 1D channels, which show tunable or switchable fluorescence signals in response to the loss of guest water molecules, have been synthesized and characterized. Especially, the chloride-bridged complex is found to be a selective fluorescence sensor for MeCN.

Original language	English
Pages (from-to)	2667-2669
Number of pages	3
Journal	Chemical Communications
Volume	47
Issue number	9
DOIs	https://doi.org/10.1039/c0cc04084c
Publication status	Published - 14 Feb 2011
Externally published	Yes

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abstract = "Two isomorphous 2D flexible metal–organic frameworks with [Cd2(μ2-X)2] (X = Cl or Br) units and dynamic 1D channels, which show tunable or switchable fluorescence signals in response to the loss of guest water molecules, have been synthesized and characterized. Especially, the chloride-bridged complex is found to be a selective fluorescence sensor for MeCN.",

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AU - Jin, Xu Hui

AU - Sun, Jian Ke

AU - Cai, Li Xuan

AU - Zhang, Jie

PY - 2011/2/14

Y1 - 2011/2/14

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AB - Two isomorphous 2D flexible metal–organic frameworks with [Cd2(μ2-X)2] (X = Cl or Br) units and dynamic 1D channels, which show tunable or switchable fluorescence signals in response to the loss of guest water molecules, have been synthesized and characterized. Especially, the chloride-bridged complex is found to be a selective fluorescence sensor for MeCN.

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DO - 10.1039/c0cc04084c

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JO - Chemical Communications

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2D flexible metal–organic frameworks with [Cd₂(μ₂-X)₂](X = Cl or Br) units exhibiting selective fluorescence sensing for small molecules

Abstract

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