Three-dimensional open-framework nickel aluminophosphate [NiAlP2O8][C2N2H9]: Assembly of one-dimensional AlP2O83- chains through [NiO5N] octahedra

Bo Wei, Jihong Yu, Zhan Shi, Shilun Qiu*, Wenfu Yan, Osamu Terasaki

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

22 引用 (Scopus)

摘要

A 3-D open-framework nickel aluminophosphate [NiAlP2O8][C2N2H9] has been solvothermally synthesized using ethylene glycol as the solvent and ethylenediamine as the template. Its structure is assembled through 1-D AlP2O83- chains with corner-sharing 4-MRs via transition metal Ni2+ ions. The 1-D AlP2O83- chains are connected through octahedral Ni atoms, which are coordinated to the terminal oxygens of 1-D AlP2O83- chains and the amino groups of the template. Infinite Ni-O-Ni chains are formed along the [001] direction.

源语言英语
页(从-至)2065-2067
页数3
期刊Chemistry of Materials
12
8
DOI
出版状态已出版 - 2000
已对外发布

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Wei, B., Yu, J., Shi, Z., Qiu, S., Yan, W., & Terasaki, O. (2000). Three-dimensional open-framework nickel aluminophosphate [NiAlP2O8][C2N2H9]: Assembly of one-dimensional AlP2O83- chains through [NiO5N] octahedra. Chemistry of Materials, 12(8), 2065-2067. https://doi.org/10.1021/cm000209b