TY - JOUR
T1 - The synthesis and structure of a chiral 1D aluminophosphate chain compound
T2 - D-Co(en)3[AlP2O8]·6.5H2O
AU - Chen, Peng
AU - Li, Jiyang
AU - Yu, Jihong
AU - Wang, Yu
AU - Pan, Qinhe
AU - Xu, Ruren
PY - 2005/6
Y1 - 2005/6
N2 - A new chiral one-dimensional (1D) aluminophosphate chain compound [d-Co(en)3][AlP2O8]·6.5H2O (designated AlPO-CJ22) has been hydrothermally synthesized by using the optically pure d-Co(en)3I3 complex as the template. Single-crystal structural analysis reveals that its structure is built up from alternating connection of AlO4 and PO2(=O2) tetrahedra to form corner-shared Al2P2 four-membered ring (4-MR) chains. The d-Co(en)33+ complex cations extended along the 21 screw axis interact with the inorganic chains through hydrogen-bonds of N⋯O atoms in a helical fashion. Optical rotation measurement shows that AlPO-CJ22 is chiral as with d-Co(en)3 3+ complex cations. Crystal data: orthorhombic, I212 121, a=8.5573(8)Å, b=22.613(2)Å, c=22.605(2)Å, Z=8, R1=0.067, wR2=0.1291, and Flack parameter: -0.02(3). CCDC number: 254179.
AB - A new chiral one-dimensional (1D) aluminophosphate chain compound [d-Co(en)3][AlP2O8]·6.5H2O (designated AlPO-CJ22) has been hydrothermally synthesized by using the optically pure d-Co(en)3I3 complex as the template. Single-crystal structural analysis reveals that its structure is built up from alternating connection of AlO4 and PO2(=O2) tetrahedra to form corner-shared Al2P2 four-membered ring (4-MR) chains. The d-Co(en)33+ complex cations extended along the 21 screw axis interact with the inorganic chains through hydrogen-bonds of N⋯O atoms in a helical fashion. Optical rotation measurement shows that AlPO-CJ22 is chiral as with d-Co(en)3 3+ complex cations. Crystal data: orthorhombic, I212 121, a=8.5573(8)Å, b=22.613(2)Å, c=22.605(2)Å, Z=8, R1=0.067, wR2=0.1291, and Flack parameter: -0.02(3). CCDC number: 254179.
KW - 1D chain
KW - Aluminophosphate
KW - Chiral structure
KW - Hydrothermal synthesis
KW - Metal complex
UR - http://www.scopus.com/inward/record.url?scp=19344364170&partnerID=8YFLogxK
U2 - 10.1016/j.jssc.2005.03.044
DO - 10.1016/j.jssc.2005.03.044
M3 - Article
AN - SCOPUS:19344364170
SN - 0022-4596
VL - 178
SP - 1929
EP - 1934
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
IS - 6
ER -