The synthesis and structure of a chiral 1D aluminophosphate chain compound: D-Co(en)3[AlP2O8]·6.5H2O

Peng Chen; Jiyang Li; Jihong Yu; Yu Wang; Qinhe Pan; Ruren Xu

doi:10.1016/j.jssc.2005.03.044

The synthesis and structure of a chiral 1D aluminophosphate chain compound: D-Co(en)₃[AlP₂O₈]·6.5H₂O

Peng Chen, Jiyang Li, Jihong Yu^*, Yu Wang, Qinhe Pan, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

A new chiral one-dimensional (1D) aluminophosphate chain compound [d-Co(en)₃][AlP₂O₈]·6.5H₂O (designated AlPO-CJ22) has been hydrothermally synthesized by using the optically pure d-Co(en)₃I₃ complex as the template. Single-crystal structural analysis reveals that its structure is built up from alternating connection of AlO₄ and PO₂(=O₂) tetrahedra to form corner-shared Al₂P₂ four-membered ring (4-MR) chains. The d-Co(en)₃³⁺ complex cations extended along the 2₁ screw axis interact with the inorganic chains through hydrogen-bonds of N⋯O atoms in a helical fashion. Optical rotation measurement shows that AlPO-CJ22 is chiral as with d-Co(en)₃ ³⁺ complex cations. Crystal data: orthorhombic, I2₁2 ₁2₁, a=8.5573(8)Å, b=22.613(2)Å, c=22.605(2)Å, Z=8, R1=0.067, wR2=0.1291, and Flack parameter: -0.02(3). CCDC number: 254179.

Original language	English
Pages (from-to)	1929-1934
Number of pages	6
Journal	Journal of Solid State Chemistry
Volume	178
Issue number	6
DOIs	https://doi.org/10.1016/j.jssc.2005.03.044
Publication status	Published - Jun 2005
Externally published	Yes

Keywords

1D chain
Aluminophosphate
Chiral structure
Hydrothermal synthesis
Metal complex

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10.1016/j.jssc.2005.03.044

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title = "The synthesis and structure of a chiral 1D aluminophosphate chain compound: D-Co(en)3[AlP2O8]·6.5H2O",

abstract = "A new chiral one-dimensional (1D) aluminophosphate chain compound [d-Co(en)3][AlP2O8]·6.5H2O (designated AlPO-CJ22) has been hydrothermally synthesized by using the optically pure d-Co(en)3I3 complex as the template. Single-crystal structural analysis reveals that its structure is built up from alternating connection of AlO4 and PO2(=O2) tetrahedra to form corner-shared Al2P2 four-membered ring (4-MR) chains. The d-Co(en)33+ complex cations extended along the 21 screw axis interact with the inorganic chains through hydrogen-bonds of N⋯O atoms in a helical fashion. Optical rotation measurement shows that AlPO-CJ22 is chiral as with d-Co(en)3 3+ complex cations. Crystal data: orthorhombic, I212 121, a=8.5573(8){\AA}, b=22.613(2){\AA}, c=22.605(2){\AA}, Z=8, R1=0.067, wR2=0.1291, and Flack parameter: -0.02(3). CCDC number: 254179.",

keywords = "1D chain, Aluminophosphate, Chiral structure, Hydrothermal synthesis, Metal complex",

author = "Peng Chen and Jiyang Li and Jihong Yu and Yu Wang and Qinhe Pan and Ruren Xu",

year = "2005",

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T1 - The synthesis and structure of a chiral 1D aluminophosphate chain compound

T2 - D-Co(en)3[AlP2O8]·6.5H2O

AU - Chen, Peng

AU - Li, Jiyang

AU - Yu, Jihong

AU - Wang, Yu

AU - Pan, Qinhe

AU - Xu, Ruren

PY - 2005/6

Y1 - 2005/6

N2 - A new chiral one-dimensional (1D) aluminophosphate chain compound [d-Co(en)3][AlP2O8]·6.5H2O (designated AlPO-CJ22) has been hydrothermally synthesized by using the optically pure d-Co(en)3I3 complex as the template. Single-crystal structural analysis reveals that its structure is built up from alternating connection of AlO4 and PO2(=O2) tetrahedra to form corner-shared Al2P2 four-membered ring (4-MR) chains. The d-Co(en)33+ complex cations extended along the 21 screw axis interact with the inorganic chains through hydrogen-bonds of N⋯O atoms in a helical fashion. Optical rotation measurement shows that AlPO-CJ22 is chiral as with d-Co(en)3 3+ complex cations. Crystal data: orthorhombic, I212 121, a=8.5573(8)Å, b=22.613(2)Å, c=22.605(2)Å, Z=8, R1=0.067, wR2=0.1291, and Flack parameter: -0.02(3). CCDC number: 254179.

AB - A new chiral one-dimensional (1D) aluminophosphate chain compound [d-Co(en)3][AlP2O8]·6.5H2O (designated AlPO-CJ22) has been hydrothermally synthesized by using the optically pure d-Co(en)3I3 complex as the template. Single-crystal structural analysis reveals that its structure is built up from alternating connection of AlO4 and PO2(=O2) tetrahedra to form corner-shared Al2P2 four-membered ring (4-MR) chains. The d-Co(en)33+ complex cations extended along the 21 screw axis interact with the inorganic chains through hydrogen-bonds of N⋯O atoms in a helical fashion. Optical rotation measurement shows that AlPO-CJ22 is chiral as with d-Co(en)3 3+ complex cations. Crystal data: orthorhombic, I212 121, a=8.5573(8)Å, b=22.613(2)Å, c=22.605(2)Å, Z=8, R1=0.067, wR2=0.1291, and Flack parameter: -0.02(3). CCDC number: 254179.

KW - 1D chain

KW - Aluminophosphate

KW - Chiral structure

KW - Hydrothermal synthesis

KW - Metal complex

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ER -

The synthesis and structure of a chiral 1D aluminophosphate chain compound: D-Co(en)₃[AlP₂O₈]·6.5H₂O

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