The enantioselective trifluoromethylation of aromatic aldehydes by quaternary ammonium bromide and (IPr)CuF at low catalyst loading

Shaoxiang Wu, Jiyi Guo, Muhammad Sohail, Chengyao Cao, Fu Xue Chen*

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

26 引用 (Scopus)

摘要

A general catalytic enantioselective trifluoromethylation of aromatic aldehydes using (IPr)CuF and quinidine-derived quaternary ammonium salt as catalysts has been developed. A wide range of aromatic aldehydes are converted to the corresponding products in up to 92% yield and 81% ee at 2 mol% of catalyst loading.

源语言英语
页(从-至)19-29
页数11
期刊Journal of Fluorine Chemistry
148
DOI
出版状态已出版 - 4月 2013

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