Synthesis, structure, and luminescent property of a heterometallic metal-organic framework constructed from rod-shaped secondary building blocks

Jianghua He; Jihong Yu; Yuetao Zhang; Qinhe Pan; Ruren Xu

doi:10.1021/ic051143v

Synthesis, structure, and luminescent property of a heterometallic metal-organic framework constructed from rod-shaped secondary building blocks

Jianghua He, Jihong Yu^*, Yuetao Zhang, Qinhe Pan, Ruren Xu

^*此作品的通讯作者

Jilin University

科研成果: 期刊稿件 › 文章 › 同行评审

242 引用（Scopus）

摘要

A new heterometallic MOF compound, [ZnNa(m-BDC)₂]·NH ₂(CH₃)₂ (MOF-CJ2), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, X-ray powder diffraction, ICP, TGA, IR, and photoluminescence spectroscopy analyses. It crystallizes in monoclinic space group C2/c (No. 15) with a = 13.277(6) Å, b = 14.323(7) Å, c = 11.328(6) Å, and β = 111.73(2)°. Its framework is constructed from M-O-C (M = Na and Zn) rods composed of alternating six-coordinated Na(I) centers and four-coordinated Zn(II) centers. These rods are linked by m-BDC links to form primitive cubic (pcu) type rod packing. This framework exemplifies the first open-framework heterometallic MOF structure based on the assembly of infinite rod building units.

源语言	英语
页（从-至）	9279-9282
页数	4
期刊	Inorganic Chemistry
卷	44
期	25
DOI	https://doi.org/10.1021/ic051143v
出版状态	已出版 - 12 12月 2005
已对外发布	是

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title = "Synthesis, structure, and luminescent property of a heterometallic metal-organic framework constructed from rod-shaped secondary building blocks",

abstract = "A new heterometallic MOF compound, [ZnNa(m-BDC)2]·NH 2(CH3)2 (MOF-CJ2), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, X-ray powder diffraction, ICP, TGA, IR, and photoluminescence spectroscopy analyses. It crystallizes in monoclinic space group C2/c (No. 15) with a = 13.277(6) {\AA}, b = 14.323(7) {\AA}, c = 11.328(6) {\AA}, and β = 111.73(2)°. Its framework is constructed from M-O-C (M = Na and Zn) rods composed of alternating six-coordinated Na(I) centers and four-coordinated Zn(II) centers. These rods are linked by m-BDC links to form primitive cubic (pcu) type rod packing. This framework exemplifies the first open-framework heterometallic MOF structure based on the assembly of infinite rod building units.",

author = "Jianghua He and Jihong Yu and Yuetao Zhang and Qinhe Pan and Ruren Xu",

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doi = "10.1021/ic051143v",

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T1 - Synthesis, structure, and luminescent property of a heterometallic metal-organic framework constructed from rod-shaped secondary building blocks

AU - He, Jianghua

AU - Yu, Jihong

AU - Zhang, Yuetao

AU - Pan, Qinhe

AU - Xu, Ruren

PY - 2005/12/12

Y1 - 2005/12/12

N2 - A new heterometallic MOF compound, [ZnNa(m-BDC)2]·NH 2(CH3)2 (MOF-CJ2), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, X-ray powder diffraction, ICP, TGA, IR, and photoluminescence spectroscopy analyses. It crystallizes in monoclinic space group C2/c (No. 15) with a = 13.277(6) Å, b = 14.323(7) Å, c = 11.328(6) Å, and β = 111.73(2)°. Its framework is constructed from M-O-C (M = Na and Zn) rods composed of alternating six-coordinated Na(I) centers and four-coordinated Zn(II) centers. These rods are linked by m-BDC links to form primitive cubic (pcu) type rod packing. This framework exemplifies the first open-framework heterometallic MOF structure based on the assembly of infinite rod building units.

AB - A new heterometallic MOF compound, [ZnNa(m-BDC)2]·NH 2(CH3)2 (MOF-CJ2), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, X-ray powder diffraction, ICP, TGA, IR, and photoluminescence spectroscopy analyses. It crystallizes in monoclinic space group C2/c (No. 15) with a = 13.277(6) Å, b = 14.323(7) Å, c = 11.328(6) Å, and β = 111.73(2)°. Its framework is constructed from M-O-C (M = Na and Zn) rods composed of alternating six-coordinated Na(I) centers and four-coordinated Zn(II) centers. These rods are linked by m-BDC links to form primitive cubic (pcu) type rod packing. This framework exemplifies the first open-framework heterometallic MOF structure based on the assembly of infinite rod building units.

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

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ER -

Synthesis, structure, and luminescent property of a heterometallic metal-organic framework constructed from rod-shaped secondary building blocks

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