Synthesis, structure, and luminescent property of a heterometallic metal-organic framework constructed from rod-shaped secondary building blocks

Jianghua He; Jihong Yu; Yuetao Zhang; Qinhe Pan; Ruren Xu

doi:10.1021/ic051143v

Synthesis, structure, and luminescent property of a heterometallic metal-organic framework constructed from rod-shaped secondary building blocks

Jianghua He, Jihong Yu^*, Yuetao Zhang, Qinhe Pan, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

242 Citations (Scopus)

Abstract

A new heterometallic MOF compound, [ZnNa(m-BDC)₂]·NH ₂(CH₃)₂ (MOF-CJ2), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, X-ray powder diffraction, ICP, TGA, IR, and photoluminescence spectroscopy analyses. It crystallizes in monoclinic space group C2/c (No. 15) with a = 13.277(6) Å, b = 14.323(7) Å, c = 11.328(6) Å, and β = 111.73(2)°. Its framework is constructed from M-O-C (M = Na and Zn) rods composed of alternating six-coordinated Na(I) centers and four-coordinated Zn(II) centers. These rods are linked by m-BDC links to form primitive cubic (pcu) type rod packing. This framework exemplifies the first open-framework heterometallic MOF structure based on the assembly of infinite rod building units.

Original language	English
Pages (from-to)	9279-9282
Number of pages	4
Journal	Inorganic Chemistry
Volume	44
Issue number	25
DOIs	https://doi.org/10.1021/ic051143v
Publication status	Published - 12 Dec 2005
Externally published	Yes

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title = "Synthesis, structure, and luminescent property of a heterometallic metal-organic framework constructed from rod-shaped secondary building blocks",

abstract = "A new heterometallic MOF compound, [ZnNa(m-BDC)2]·NH 2(CH3)2 (MOF-CJ2), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, X-ray powder diffraction, ICP, TGA, IR, and photoluminescence spectroscopy analyses. It crystallizes in monoclinic space group C2/c (No. 15) with a = 13.277(6) {\AA}, b = 14.323(7) {\AA}, c = 11.328(6) {\AA}, and β = 111.73(2)°. Its framework is constructed from M-O-C (M = Na and Zn) rods composed of alternating six-coordinated Na(I) centers and four-coordinated Zn(II) centers. These rods are linked by m-BDC links to form primitive cubic (pcu) type rod packing. This framework exemplifies the first open-framework heterometallic MOF structure based on the assembly of infinite rod building units.",

author = "Jianghua He and Jihong Yu and Yuetao Zhang and Qinhe Pan and Ruren Xu",

year = "2005",

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doi = "10.1021/ic051143v",

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journal = "Inorganic Chemistry",

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T1 - Synthesis, structure, and luminescent property of a heterometallic metal-organic framework constructed from rod-shaped secondary building blocks

AU - He, Jianghua

AU - Yu, Jihong

AU - Zhang, Yuetao

AU - Pan, Qinhe

AU - Xu, Ruren

PY - 2005/12/12

Y1 - 2005/12/12

N2 - A new heterometallic MOF compound, [ZnNa(m-BDC)2]·NH 2(CH3)2 (MOF-CJ2), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, X-ray powder diffraction, ICP, TGA, IR, and photoluminescence spectroscopy analyses. It crystallizes in monoclinic space group C2/c (No. 15) with a = 13.277(6) Å, b = 14.323(7) Å, c = 11.328(6) Å, and β = 111.73(2)°. Its framework is constructed from M-O-C (M = Na and Zn) rods composed of alternating six-coordinated Na(I) centers and four-coordinated Zn(II) centers. These rods are linked by m-BDC links to form primitive cubic (pcu) type rod packing. This framework exemplifies the first open-framework heterometallic MOF structure based on the assembly of infinite rod building units.

AB - A new heterometallic MOF compound, [ZnNa(m-BDC)2]·NH 2(CH3)2 (MOF-CJ2), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, X-ray powder diffraction, ICP, TGA, IR, and photoluminescence spectroscopy analyses. It crystallizes in monoclinic space group C2/c (No. 15) with a = 13.277(6) Å, b = 14.323(7) Å, c = 11.328(6) Å, and β = 111.73(2)°. Its framework is constructed from M-O-C (M = Na and Zn) rods composed of alternating six-coordinated Na(I) centers and four-coordinated Zn(II) centers. These rods are linked by m-BDC links to form primitive cubic (pcu) type rod packing. This framework exemplifies the first open-framework heterometallic MOF structure based on the assembly of infinite rod building units.

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M3 - Article

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SN - 0020-1669

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SP - 9279

EP - 9282

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 25

ER -

Synthesis, structure, and luminescent property of a heterometallic metal-organic framework constructed from rod-shaped secondary building blocks

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