Synthesis and properties of insensitive [1,2,4]triazolo[4,3-b]-1,2,4,5-tetrazine explosives

Guilong Wang; Tian Lu; Guijuan Fan; Hongquan Yin; Fu Xue Chen

doi:10.1039/C8NJ05220D

Synthesis and properties of insensitive [1,2,4]triazolo[4,3-b]-1,2,4,5-tetrazine explosives

Guilong Wang, Tian Lu, Guijuan Fan, Hongquan Yin, Fu Xue Chen^*

^*此作品的通讯作者

化学与化工学院

科研成果: 期刊稿件 › 文章 › 同行评审

29 引用（Scopus）

摘要

By taking advantage of thermostable 1,2,4,5-tetrazine and energetic 1,2,4-triazole rings, two [1,2,4]triazolo[4,3-b]1,2,4,5-tetrazine explosives were synthesized and fully characterized. Based on experimental and computational data, 3-nitro-[1,2,4]triazolo[4,3-b]1,2,4,5-tetrazin-6-amine (TTNA) was found to demonstrate properties such as a suitable density (1.83 g cm⁻³), favourable thermal stability (T_d, 213 °C), good detonation performance (P, 33.9 GPa; V_D, 8953 m s⁻¹) and low impact sensitivity (IS > 40 J, FS > 360 N).

源语言	英语
页（从-至）	1663-1666
页数	4
期刊	New Journal of Chemistry
卷	43
期	4
DOI	https://doi.org/10.1039/C8NJ05220D
出版状态	已出版 - 2019

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10.1039/C8NJ05220D

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引用此

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title = "Synthesis and properties of insensitive [1,2,4]triazolo[4,3-b]-1,2,4,5-tetrazine explosives",

abstract = "By taking advantage of thermostable 1,2,4,5-tetrazine and energetic 1,2,4-triazole rings, two [1,2,4]triazolo[4,3-b]1,2,4,5-tetrazine explosives were synthesized and fully characterized. Based on experimental and computational data, 3-nitro-[1,2,4]triazolo[4,3-b]1,2,4,5-tetrazin-6-amine (TTNA) was found to demonstrate properties such as a suitable density (1.83 g cm−3), favourable thermal stability (Td, 213 °C), good detonation performance (P, 33.9 GPa; VD, 8953 m s−1) and low impact sensitivity (IS > 40 J, FS > 360 N).",

author = "Guilong Wang and Tian Lu and Guijuan Fan and Hongquan Yin and Chen, {Fu Xue}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.",

year = "2019",

doi = "10.1039/C8NJ05220D",

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T1 - Synthesis and properties of insensitive [1,2,4]triazolo[4,3-b]-1,2,4,5-tetrazine explosives

AU - Wang, Guilong

AU - Lu, Tian

AU - Fan, Guijuan

AU - Yin, Hongquan

AU - Chen, Fu Xue

PY - 2019

Y1 - 2019

N2 - By taking advantage of thermostable 1,2,4,5-tetrazine and energetic 1,2,4-triazole rings, two [1,2,4]triazolo[4,3-b]1,2,4,5-tetrazine explosives were synthesized and fully characterized. Based on experimental and computational data, 3-nitro-[1,2,4]triazolo[4,3-b]1,2,4,5-tetrazin-6-amine (TTNA) was found to demonstrate properties such as a suitable density (1.83 g cm−3), favourable thermal stability (Td, 213 °C), good detonation performance (P, 33.9 GPa; VD, 8953 m s−1) and low impact sensitivity (IS > 40 J, FS > 360 N).

AB - By taking advantage of thermostable 1,2,4,5-tetrazine and energetic 1,2,4-triazole rings, two [1,2,4]triazolo[4,3-b]1,2,4,5-tetrazine explosives were synthesized and fully characterized. Based on experimental and computational data, 3-nitro-[1,2,4]triazolo[4,3-b]1,2,4,5-tetrazin-6-amine (TTNA) was found to demonstrate properties such as a suitable density (1.83 g cm−3), favourable thermal stability (Td, 213 °C), good detonation performance (P, 33.9 GPa; VD, 8953 m s−1) and low impact sensitivity (IS > 40 J, FS > 360 N).

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