TY - JOUR
T1 - Synthesis and properties of insensitive [1,2,4]triazolo[4,3-b]-1,2,4,5-tetrazine explosives
AU - Wang, Guilong
AU - Lu, Tian
AU - Fan, Guijuan
AU - Yin, Hongquan
AU - Chen, Fu Xue
N1 - Publisher Copyright:
© The Royal Society of Chemistry and the Centre National de la Recherche Scientifique.
PY - 2019
Y1 - 2019
N2 - By taking advantage of thermostable 1,2,4,5-tetrazine and energetic 1,2,4-triazole rings, two [1,2,4]triazolo[4,3-b]1,2,4,5-tetrazine explosives were synthesized and fully characterized. Based on experimental and computational data, 3-nitro-[1,2,4]triazolo[4,3-b]1,2,4,5-tetrazin-6-amine (TTNA) was found to demonstrate properties such as a suitable density (1.83 g cm−3), favourable thermal stability (Td, 213 °C), good detonation performance (P, 33.9 GPa; VD, 8953 m s−1) and low impact sensitivity (IS > 40 J, FS > 360 N).
AB - By taking advantage of thermostable 1,2,4,5-tetrazine and energetic 1,2,4-triazole rings, two [1,2,4]triazolo[4,3-b]1,2,4,5-tetrazine explosives were synthesized and fully characterized. Based on experimental and computational data, 3-nitro-[1,2,4]triazolo[4,3-b]1,2,4,5-tetrazin-6-amine (TTNA) was found to demonstrate properties such as a suitable density (1.83 g cm−3), favourable thermal stability (Td, 213 °C), good detonation performance (P, 33.9 GPa; VD, 8953 m s−1) and low impact sensitivity (IS > 40 J, FS > 360 N).
UR - http://www.scopus.com/inward/record.url?scp=85060371972&partnerID=8YFLogxK
U2 - 10.1039/C8NJ05220D
DO - 10.1039/C8NJ05220D
M3 - Article
AN - SCOPUS:85060371972
SN - 1144-0546
VL - 43
SP - 1663
EP - 1666
JO - New Journal of Chemistry
JF - New Journal of Chemistry
IS - 4
ER -