Synthesis and characterization of GZT

Yi Hui Wang; Zhi Ming Du; Chun Lin He; Xiao Min Cong; Hong She Wang; Chun Ying Wang

Synthesis and characterization of GZT

Yi Hui Wang^*, Zhi Ming Du, Chun Lin He, Xiao Min Cong, Hong She Wang, Chun Ying Wang

^*此作品的通讯作者

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

11 引用（Scopus）

摘要

Guanidinium azotetrazolate (GZT) was synthesized from 5-aminotetrazole (5-AT) by oxidation-reduction reaction and chemical combination reaction. The effects of reaction temperature, reaction time, molar ratio of reactants and NaOH concentration on the reaction were discussed. The proper technological conditions were identified as follows: based on 0.1 mol of 5-AT, NaOH concentration 1.5 mol · L^-1, n(5-AT):n(KMnO₄) = 3:3, reaction temperature 80°C, reaction time 60 min. Under the known optimum conditions, scale-up test is made and the yield is more than 80%. The structure and characterization of the compound were characterized by element analysis, IR, ¹H-NMR and TG-DTA technology.

源语言	英语
页（从-至）	581-584
页数	4
期刊	Hanneng Cailiao/Chinese Journal of Energetic Materials
卷	16
期	5
出版状态	已出版 - 10月 2008

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title = "Synthesis and characterization of GZT",

abstract = "Guanidinium azotetrazolate (GZT) was synthesized from 5-aminotetrazole (5-AT) by oxidation-reduction reaction and chemical combination reaction. The effects of reaction temperature, reaction time, molar ratio of reactants and NaOH concentration on the reaction were discussed. The proper technological conditions were identified as follows: based on 0.1 mol of 5-AT, NaOH concentration 1.5 mol · L-1, n(5-AT):n(KMnO4) = 3:3, reaction temperature 80°C, reaction time 60 min. Under the known optimum conditions, scale-up test is made and the yield is more than 80%. The structure and characterization of the compound were characterized by element analysis, IR, 1H-NMR and TG-DTA technology.",

keywords = "5-aminotetrazole (5-AT), Applied chemistry, Guanidinium azotetrazolate (GZT), High-nitrogen compound",

author = "Wang, {Yi Hui} and Du, {Zhi Ming} and He, {Chun Lin} and Cong, {Xiao Min} and Wang, {Hong She} and Wang, {Chun Ying}",

year = "2008",

month = oct,

language = "English",

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pages = "581--584",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Chinese Academy of Engineering Physics",

number = "5",

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TY - JOUR

T1 - Synthesis and characterization of GZT

AU - Wang, Yi Hui

AU - Du, Zhi Ming

AU - He, Chun Lin

AU - Cong, Xiao Min

AU - Wang, Hong She

AU - Wang, Chun Ying

PY - 2008/10

Y1 - 2008/10

N2 - Guanidinium azotetrazolate (GZT) was synthesized from 5-aminotetrazole (5-AT) by oxidation-reduction reaction and chemical combination reaction. The effects of reaction temperature, reaction time, molar ratio of reactants and NaOH concentration on the reaction were discussed. The proper technological conditions were identified as follows: based on 0.1 mol of 5-AT, NaOH concentration 1.5 mol · L-1, n(5-AT):n(KMnO4) = 3:3, reaction temperature 80°C, reaction time 60 min. Under the known optimum conditions, scale-up test is made and the yield is more than 80%. The structure and characterization of the compound were characterized by element analysis, IR, 1H-NMR and TG-DTA technology.

AB - Guanidinium azotetrazolate (GZT) was synthesized from 5-aminotetrazole (5-AT) by oxidation-reduction reaction and chemical combination reaction. The effects of reaction temperature, reaction time, molar ratio of reactants and NaOH concentration on the reaction were discussed. The proper technological conditions were identified as follows: based on 0.1 mol of 5-AT, NaOH concentration 1.5 mol · L-1, n(5-AT):n(KMnO4) = 3:3, reaction temperature 80°C, reaction time 60 min. Under the known optimum conditions, scale-up test is made and the yield is more than 80%. The structure and characterization of the compound were characterized by element analysis, IR, 1H-NMR and TG-DTA technology.

KW - 5-aminotetrazole (5-AT)

KW - Applied chemistry

KW - Guanidinium azotetrazolate (GZT)

KW - High-nitrogen compound

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M3 - Article

AN - SCOPUS:57149090584

SN - 1006-9941

VL - 16

SP - 581

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JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 5

ER -

Synthesis and characterization of GZT

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