Synthesis and characterization of GZT

Yi Hui Wang; Zhi Ming Du; Chun Lin He; Xiao Min Cong; Hong She Wang; Chun Ying Wang

Synthesis and characterization of GZT

Yi Hui Wang^*, Zhi Ming Du, Chun Lin He, Xiao Min Cong, Hong She Wang, Chun Ying Wang

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

11 Citations (Scopus)

Abstract

Guanidinium azotetrazolate (GZT) was synthesized from 5-aminotetrazole (5-AT) by oxidation-reduction reaction and chemical combination reaction. The effects of reaction temperature, reaction time, molar ratio of reactants and NaOH concentration on the reaction were discussed. The proper technological conditions were identified as follows: based on 0.1 mol of 5-AT, NaOH concentration 1.5 mol · L^-1, n(5-AT):n(KMnO₄) = 3:3, reaction temperature 80°C, reaction time 60 min. Under the known optimum conditions, scale-up test is made and the yield is more than 80%. The structure and characterization of the compound were characterized by element analysis, IR, ¹H-NMR and TG-DTA technology.

Original language	English
Pages (from-to)	581-584
Number of pages	4
Journal	Hanneng Cailiao/Chinese Journal of Energetic Materials
Volume	16
Issue number	5
Publication status	Published - Oct 2008

Keywords

5-aminotetrazole (5-AT)
Applied chemistry
Guanidinium azotetrazolate (GZT)
High-nitrogen compound

Cite this

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title = "Synthesis and characterization of GZT",

abstract = "Guanidinium azotetrazolate (GZT) was synthesized from 5-aminotetrazole (5-AT) by oxidation-reduction reaction and chemical combination reaction. The effects of reaction temperature, reaction time, molar ratio of reactants and NaOH concentration on the reaction were discussed. The proper technological conditions were identified as follows: based on 0.1 mol of 5-AT, NaOH concentration 1.5 mol · L-1, n(5-AT):n(KMnO4) = 3:3, reaction temperature 80°C, reaction time 60 min. Under the known optimum conditions, scale-up test is made and the yield is more than 80%. The structure and characterization of the compound were characterized by element analysis, IR, 1H-NMR and TG-DTA technology.",

keywords = "5-aminotetrazole (5-AT), Applied chemistry, Guanidinium azotetrazolate (GZT), High-nitrogen compound",

author = "Wang, {Yi Hui} and Du, {Zhi Ming} and He, {Chun Lin} and Cong, {Xiao Min} and Wang, {Hong She} and Wang, {Chun Ying}",

year = "2008",

month = oct,

language = "English",

volume = "16",

pages = "581--584",

journal = "Hanneng Cailiao/Chinese Journal of Energetic Materials",

issn = "1006-9941",

publisher = "Institute of Chemical Materials, China Academy of Engineering Physics",

number = "5",

}

TY - JOUR

T1 - Synthesis and characterization of GZT

AU - Wang, Yi Hui

AU - Du, Zhi Ming

AU - He, Chun Lin

AU - Cong, Xiao Min

AU - Wang, Hong She

AU - Wang, Chun Ying

PY - 2008/10

Y1 - 2008/10

N2 - Guanidinium azotetrazolate (GZT) was synthesized from 5-aminotetrazole (5-AT) by oxidation-reduction reaction and chemical combination reaction. The effects of reaction temperature, reaction time, molar ratio of reactants and NaOH concentration on the reaction were discussed. The proper technological conditions were identified as follows: based on 0.1 mol of 5-AT, NaOH concentration 1.5 mol · L-1, n(5-AT):n(KMnO4) = 3:3, reaction temperature 80°C, reaction time 60 min. Under the known optimum conditions, scale-up test is made and the yield is more than 80%. The structure and characterization of the compound were characterized by element analysis, IR, 1H-NMR and TG-DTA technology.

AB - Guanidinium azotetrazolate (GZT) was synthesized from 5-aminotetrazole (5-AT) by oxidation-reduction reaction and chemical combination reaction. The effects of reaction temperature, reaction time, molar ratio of reactants and NaOH concentration on the reaction were discussed. The proper technological conditions were identified as follows: based on 0.1 mol of 5-AT, NaOH concentration 1.5 mol · L-1, n(5-AT):n(KMnO4) = 3:3, reaction temperature 80°C, reaction time 60 min. Under the known optimum conditions, scale-up test is made and the yield is more than 80%. The structure and characterization of the compound were characterized by element analysis, IR, 1H-NMR and TG-DTA technology.

KW - 5-aminotetrazole (5-AT)

KW - Applied chemistry

KW - Guanidinium azotetrazolate (GZT)

KW - High-nitrogen compound

UR - http://www.scopus.com/inward/record.url?scp=57149090584&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:57149090584

SN - 1006-9941

VL - 16

SP - 581

EP - 584

JO - Hanneng Cailiao/Chinese Journal of Energetic Materials

JF - Hanneng Cailiao/Chinese Journal of Energetic Materials

IS - 5

ER -

Synthesis and characterization of GZT

Abstract

Keywords

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