7Li NMR Spectroscopy: a Tool for Determining Dimerization Constants and Averaged Dimerization Constants of the Monomer/Dimer Equilibrium of Hierarchical Helicates

Tobias Krückel, Steffen Schauerte, Jinbo Ke, Marcel Schlottmann, Sandra Bausch, Xiaofei Chen, Christoph Räuber, Igor d.Anciães Almeida Silva, Thomas Wiegand, Markus Albrecht*

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

摘要

7Li nuclear magnetic resonance (NMR) spectroscopy is an ideal tool to study hierarchically assembled helicates of the form Li[Li3L6Ti2]. Internally bound and external lithium ions can be well distinguished by solution- or solid-state NMR spectroscopy and dimerization constants of the monomer/dimer equilibrium can be easily determined in solution. Averaged dimerization constants can be estimated in case of statistical mixtures of helicates formed from mixtures of ligands.

源语言英语
期刊Chemistry - A European Journal
DOI
出版状态已接受/待刊 - 2024
已对外发布

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