Abstract
7Li nuclear magnetic resonance (NMR) spectroscopy is an ideal tool to study hierarchically assembled helicates of the form Li[Li3L6Ti2]. Internally bound and external lithium ions can be well distinguished by solution- or solid-state NMR spectroscopy and dimerization constants of the monomer/dimer equilibrium can be easily determined in solution. Averaged dimerization constants can be estimated in case of statistical mixtures of helicates formed from mixtures of ligands.
Original language | English |
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Journal | Chemistry - A European Journal |
DOIs | |
Publication status | Accepted/In press - 2024 |
Externally published | Yes |
Keywords
- Hierarchical helicate
- Li NMR
- coordination chemistry
- equilibrium
- thermodynamic