Stabilization of Grignard reagents by a pillar[5]arene host-Schlenk equilibria and Grignard reactions

Lingyi Shen, Yanxia Zhao, Dihua Dai, Ying Wei Yang*, Biao Wu, Xiao Juan Yang

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

15 引用 (Scopus)

摘要

Grignard reagents (RMgX) are widely used in organic synthesis. However, these highly reactive compounds are supplied in inflammable solvents, which causes extra complexity in their transportation. Herein we report that Grignard reagents with linear alkyl chains can be entrapped and stabilized by the macrocyclic host pillar[5]arene while preserving their reactivity.

源语言英语
页(从-至)1381-1384
页数4
期刊Chemical Communications
56
9
DOI
出版状态已出版 - 2020
已对外发布

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