Preparation of trifluoroiodomethane via vapor-phase catalytic reaction between hexafluoropropylene oxide and iodine

Guang Cheng Yang, Xiao Qing Jia, Ren Ming Pan, Heng Dao Quan*

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

12 引用 (Scopus)

摘要

Based on our previous investigation on the reaction mechanism to produce difluorocarbene and subsequent CF3I starting with CHF3 and I2, a new route for preparing CF3I at a relative low temperature, 200 °C, has been developed via a vapor-phase catalytic reaction between hexafluoropropylene oxide with I2 in the presence of KF supported on activate charcoal as a catalyst. The influence of reaction temperature and reaction time on the amount of CF3I was investigated. In the reaction process, coke-formation was suggested on the surface of catalysts by means of BET, XPS and TG-DTA analysis. The process for the formation of CF3I and by-products is also discussed.

源语言英语
页(从-至)985-988
页数4
期刊Journal of Fluorine Chemistry
130
10
DOI
出版状态已出版 - 10月 2009
已对外发布

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