Preparation of trifluoroiodomethane via vapor-phase catalytic reaction between hexafluoropropylene oxide and iodine

Guang Cheng Yang; Xiao Qing Jia; Ren Ming Pan; Heng Dao Quan

doi:10.1016/j.jfluchem.2009.06.010

Preparation of trifluoroiodomethane via vapor-phase catalytic reaction between hexafluoropropylene oxide and iodine

Guang Cheng Yang, Xiao Qing Jia, Ren Ming Pan, Heng Dao Quan^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

12 Citations (Scopus)

Abstract

Based on our previous investigation on the reaction mechanism to produce difluorocarbene and subsequent CF₃I starting with CHF₃ and I₂, a new route for preparing CF₃I at a relative low temperature, 200 °C, has been developed via a vapor-phase catalytic reaction between hexafluoropropylene oxide with I₂ in the presence of KF supported on activate charcoal as a catalyst. The influence of reaction temperature and reaction time on the amount of CF₃I was investigated. In the reaction process, coke-formation was suggested on the surface of catalysts by means of BET, XPS and TG-DTA analysis. The process for the formation of CF₃I and by-products is also discussed.

Original language	English
Pages (from-to)	985-988
Number of pages	4
Journal	Journal of Fluorine Chemistry
Volume	130
Issue number	10
DOIs	https://doi.org/10.1016/j.jfluchem.2009.06.010
Publication status	Published - Oct 2009
Externally published	Yes

Keywords

CF carbene
CFI
Disproportionation
Hexafluoropropylene oxide

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10.1016/j.jfluchem.2009.06.010

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Yang, G. C., Jia, X. Q., Pan, R. M., & Quan, H. D. (2009). Preparation of trifluoroiodomethane via vapor-phase catalytic reaction between hexafluoropropylene oxide and iodine. Journal of Fluorine Chemistry, 130(10), 985-988. https://doi.org/10.1016/j.jfluchem.2009.06.010

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title = "Preparation of trifluoroiodomethane via vapor-phase catalytic reaction between hexafluoropropylene oxide and iodine",

abstract = "Based on our previous investigation on the reaction mechanism to produce difluorocarbene and subsequent CF3I starting with CHF3 and I2, a new route for preparing CF3I at a relative low temperature, 200 °C, has been developed via a vapor-phase catalytic reaction between hexafluoropropylene oxide with I2 in the presence of KF supported on activate charcoal as a catalyst. The influence of reaction temperature and reaction time on the amount of CF3I was investigated. In the reaction process, coke-formation was suggested on the surface of catalysts by means of BET, XPS and TG-DTA analysis. The process for the formation of CF3I and by-products is also discussed.",

keywords = "CF carbene, CFI, Disproportionation, Hexafluoropropylene oxide",

author = "Yang, {Guang Cheng} and Jia, {Xiao Qing} and Pan, {Ren Ming} and Quan, {Heng Dao}",

year = "2009",

month = oct,

doi = "10.1016/j.jfluchem.2009.06.010",

language = "English",

volume = "130",

pages = "985--988",

journal = "Journal of Fluorine Chemistry",

issn = "0022-1139",

publisher = "Elsevier B.V.",

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T1 - Preparation of trifluoroiodomethane via vapor-phase catalytic reaction between hexafluoropropylene oxide and iodine

AU - Yang, Guang Cheng

AU - Jia, Xiao Qing

AU - Pan, Ren Ming

AU - Quan, Heng Dao

PY - 2009/10

Y1 - 2009/10

N2 - Based on our previous investigation on the reaction mechanism to produce difluorocarbene and subsequent CF3I starting with CHF3 and I2, a new route for preparing CF3I at a relative low temperature, 200 °C, has been developed via a vapor-phase catalytic reaction between hexafluoropropylene oxide with I2 in the presence of KF supported on activate charcoal as a catalyst. The influence of reaction temperature and reaction time on the amount of CF3I was investigated. In the reaction process, coke-formation was suggested on the surface of catalysts by means of BET, XPS and TG-DTA analysis. The process for the formation of CF3I and by-products is also discussed.

AB - Based on our previous investigation on the reaction mechanism to produce difluorocarbene and subsequent CF3I starting with CHF3 and I2, a new route for preparing CF3I at a relative low temperature, 200 °C, has been developed via a vapor-phase catalytic reaction between hexafluoropropylene oxide with I2 in the presence of KF supported on activate charcoal as a catalyst. The influence of reaction temperature and reaction time on the amount of CF3I was investigated. In the reaction process, coke-formation was suggested on the surface of catalysts by means of BET, XPS and TG-DTA analysis. The process for the formation of CF3I and by-products is also discussed.

KW - CF carbene

KW - CFI

KW - Disproportionation

KW - Hexafluoropropylene oxide

UR - http://www.scopus.com/inward/record.url?scp=70249108099&partnerID=8YFLogxK

U2 - 10.1016/j.jfluchem.2009.06.010

DO - 10.1016/j.jfluchem.2009.06.010

M3 - Article

AN - SCOPUS:70249108099

SN - 0022-1139

VL - 130

SP - 985

EP - 988

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 10

ER -

Preparation of trifluoroiodomethane via vapor-phase catalytic reaction between hexafluoropropylene oxide and iodine

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Keywords

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