TY - JOUR
T1 - [Ni(1,2-PDA)3]2(HOCH2CH2CH 2NH3)3(H3O)2 [Ge 7O14X3]3 (X = F, OH)
T2 - A new 1D germanate with 12-ring hexagonal tubular channels
AU - Pan, Qinhe
AU - Li, Jiyang
AU - Ren, Xiaoyan
AU - Wang, Zhuopeng
AU - Li, Guanghua
AU - Yu, Jihong
AU - Xu, Ruren
PY - 2008/1/22
Y1 - 2008/1/22
N2 - A novel one-dimensional germante JLG-4, [Ni(1,2-diaminopropane) 3]2(HOCH2CH2CH2NH 3)3(H3O)2[Ge7O 14X3]3 (X= F, OH), with 12-ring hexagonal tubular channels has been prepared. The 12-ring tube comprising 10-ring windows is produced by corner-sharing of Ge7 clusters. The metal complex [Ni(1,2-PDA)3]2+ is self-assembled during the solvothermal synthesis and acts as the structure-directing agent (SDA) along with 3-amino-1-propanol that acts as SDA and solvent. By using the auto assembly secondary building unit (AASBU) approach, new open-framework germanate structures with large pores and low-framework density can also be designed by using Ge7 clusters as SBUs.
AB - A novel one-dimensional germante JLG-4, [Ni(1,2-diaminopropane) 3]2(HOCH2CH2CH2NH 3)3(H3O)2[Ge7O 14X3]3 (X= F, OH), with 12-ring hexagonal tubular channels has been prepared. The 12-ring tube comprising 10-ring windows is produced by corner-sharing of Ge7 clusters. The metal complex [Ni(1,2-PDA)3]2+ is self-assembled during the solvothermal synthesis and acts as the structure-directing agent (SDA) along with 3-amino-1-propanol that acts as SDA and solvent. By using the auto assembly secondary building unit (AASBU) approach, new open-framework germanate structures with large pores and low-framework density can also be designed by using Ge7 clusters as SBUs.
UR - http://www.scopus.com/inward/record.url?scp=38949175382&partnerID=8YFLogxK
U2 - 10.1021/cm702439v
DO - 10.1021/cm702439v
M3 - Article
AN - SCOPUS:38949175382
SN - 0897-4756
VL - 20
SP - 370
EP - 372
JO - Chemistry of Materials
JF - Chemistry of Materials
IS - 2
ER -