[Ni(1,2-PDA)3]2(HOCH2CH2CH 2NH3)3(H3O)2 [Ge 7O14X3]3 (X = F, OH): A new 1D germanate with 12-ring hexagonal tubular channels

Qinhe Pan; Jiyang Li; Xiaoyan Ren; Zhuopeng Wang; Guanghua Li; Jihong Yu; Ruren Xu

doi:10.1021/cm702439v

[Ni(1,2-PDA)₃]₂(HOCH₂CH₂CH ₂NH₃)₃(H₃O)₂ [Ge ₇O₁₄X₃]₃ (X = F, OH): A new 1D germanate with 12-ring hexagonal tubular channels

Qinhe Pan, Jiyang Li, Xiaoyan Ren, Zhuopeng Wang, Guanghua Li, Jihong Yu^*, Ruren Xu

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

A novel one-dimensional germante JLG-4, [Ni(1,2-diaminopropane) ₃]₂(HOCH₂CH₂CH₂NH ₃)₃(H₃O)₂[Ge₇O ₁₄X₃]₃ (X= F, OH), with 12-ring hexagonal tubular channels has been prepared. The 12-ring tube comprising 10-ring windows is produced by corner-sharing of Ge₇ clusters. The metal complex [Ni(1,2-PDA)₃]²⁺ is self-assembled during the solvothermal synthesis and acts as the structure-directing agent (SDA) along with 3-amino-1-propanol that acts as SDA and solvent. By using the auto assembly secondary building unit (AASBU) approach, new open-framework germanate structures with large pores and low-framework density can also be designed by using Ge₇ clusters as SBUs.

Original language	English
Pages (from-to)	370-372
Number of pages	3
Journal	Chemistry of Materials
Volume	20
Issue number	2
DOIs	https://doi.org/10.1021/cm702439v
Publication status	Published - 22 Jan 2008
Externally published	Yes

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Pan, Q., Li, J., Ren, X., Wang, Z., Li, G., Yu, J., & Xu, R. (2008). [Ni(1,2-PDA)₃]₂(HOCH₂CH₂CH ₂NH₃)₃(H₃O)₂ [Ge ₇O₁₄X₃]₃ (X = F, OH): A new 1D germanate with 12-ring hexagonal tubular channels. Chemistry of Materials, 20(2), 370-372. https://doi.org/10.1021/cm702439v

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title = "[Ni(1,2-PDA)3]2(HOCH2CH2CH 2NH3)3(H3O)2 [Ge 7O14X3]3 (X = F, OH): A new 1D germanate with 12-ring hexagonal tubular channels",

abstract = "A novel one-dimensional germante JLG-4, [Ni(1,2-diaminopropane) 3]2(HOCH2CH2CH2NH 3)3(H3O)2[Ge7O 14X3]3 (X= F, OH), with 12-ring hexagonal tubular channels has been prepared. The 12-ring tube comprising 10-ring windows is produced by corner-sharing of Ge7 clusters. The metal complex [Ni(1,2-PDA)3]2+ is self-assembled during the solvothermal synthesis and acts as the structure-directing agent (SDA) along with 3-amino-1-propanol that acts as SDA and solvent. By using the auto assembly secondary building unit (AASBU) approach, new open-framework germanate structures with large pores and low-framework density can also be designed by using Ge7 clusters as SBUs.",

author = "Qinhe Pan and Jiyang Li and Xiaoyan Ren and Zhuopeng Wang and Guanghua Li and Jihong Yu and Ruren Xu",

year = "2008",

month = jan,

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doi = "10.1021/cm702439v",

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journal = "Chemistry of Materials",

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T1 - [Ni(1,2-PDA)3]2(HOCH2CH2CH 2NH3)3(H3O)2 [Ge 7O14X3]3 (X = F, OH)

T2 - A new 1D germanate with 12-ring hexagonal tubular channels

AU - Pan, Qinhe

AU - Li, Jiyang

AU - Ren, Xiaoyan

AU - Wang, Zhuopeng

AU - Li, Guanghua

AU - Yu, Jihong

AU - Xu, Ruren

PY - 2008/1/22

Y1 - 2008/1/22

N2 - A novel one-dimensional germante JLG-4, [Ni(1,2-diaminopropane) 3]2(HOCH2CH2CH2NH 3)3(H3O)2[Ge7O 14X3]3 (X= F, OH), with 12-ring hexagonal tubular channels has been prepared. The 12-ring tube comprising 10-ring windows is produced by corner-sharing of Ge7 clusters. The metal complex [Ni(1,2-PDA)3]2+ is self-assembled during the solvothermal synthesis and acts as the structure-directing agent (SDA) along with 3-amino-1-propanol that acts as SDA and solvent. By using the auto assembly secondary building unit (AASBU) approach, new open-framework germanate structures with large pores and low-framework density can also be designed by using Ge7 clusters as SBUs.

AB - A novel one-dimensional germante JLG-4, [Ni(1,2-diaminopropane) 3]2(HOCH2CH2CH2NH 3)3(H3O)2[Ge7O 14X3]3 (X= F, OH), with 12-ring hexagonal tubular channels has been prepared. The 12-ring tube comprising 10-ring windows is produced by corner-sharing of Ge7 clusters. The metal complex [Ni(1,2-PDA)3]2+ is self-assembled during the solvothermal synthesis and acts as the structure-directing agent (SDA) along with 3-amino-1-propanol that acts as SDA and solvent. By using the auto assembly secondary building unit (AASBU) approach, new open-framework germanate structures with large pores and low-framework density can also be designed by using Ge7 clusters as SBUs.

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U2 - 10.1021/cm702439v

DO - 10.1021/cm702439v

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VL - 20

SP - 370

EP - 372

JO - Chemistry of Materials

JF - Chemistry of Materials

IS - 2

ER -

[Ni(1,2-PDA)₃]₂(HOCH₂CH₂CH ₂NH₃)₃(H₃O)₂ [Ge ₇O₁₄X₃]₃ (X = F, OH): A new 1D germanate with 12-ring hexagonal tubular channels

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