Identification of PEO-PPO-PEO triblock copolymer by PGC/MS

Guiling Niu*, Aiqin Luo, Ruonong Fu, Mei Wang, Yufang Sun, Xianlun Wang, Sheng Jin

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

摘要

Aim: To identify PEO-PPO-PEO triblock copolymer using PGC/MS techniques. Methods: The polyethylene oxide (PEO), polypropylene oxide (PPO) and PEO-PPO-PEO triblock copolymers were analyzed by pyrolysis gas chromatography/mass spectrometry (PGC/MS) under suitable operating condition. Results and Conclusion: On total ion chromatograms of PGC/MS for PEO-PPO-PEO triblock copolymers the hybrid characteristic pyrolyzates were found at 16.13 min. These two compounds are very useful to confirm the copolymer structure and the copolymerization processes. The possible fracture position of hybrid dimers in mass spectrometry were deduced.

源语言英语
页(从-至)375-379
页数5
期刊Beijing Ligong Daxue Xuebao/Transaction of Beijing Institute of Technology
18
3
出版状态已出版 - 1998

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