Fluorination of n-dodecane adsorbed on porous aluminium fluoride by gaseous fluorine

Heng Dao Quan; Masanori Tamura; Toshiyuki Takagi; Akira Sekiya

doi:10.1016/S0022-1139(99)00134-7

Fluorination of n-dodecane adsorbed on porous aluminium fluoride by gaseous fluorine

Heng Dao Quan^*, Masanori Tamura, Toshiyuki Takagi, Akira Sekiya

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9 引用（Scopus）

摘要

The reaction of fluorine with n-dodecane adsorbed on porous aluminium fluoride (PAF) proceeds with up to 90% selectivity for all monofluorinated dodecane and more than 30% selectivity for terminal fluorinated dodecane, which provides a novel means for preparing mono and terminal linear fluorinated alkanes. In the reaction, PAF with a large surface area is chosen as support to adsorb the linear hydrocarbon.

源语言	英语
页（从-至）	167-170
页数	4
期刊	Journal of Fluorine Chemistry
卷	99
期	2
DOI	https://doi.org/10.1016/S0022-1139(99)00134-7
出版状态	已出版 - 11月 1999
已对外发布	是

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10.1016/S0022-1139(99)00134-7

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title = "Fluorination of n-dodecane adsorbed on porous aluminium fluoride by gaseous fluorine",

abstract = "The reaction of fluorine with n-dodecane adsorbed on porous aluminium fluoride (PAF) proceeds with up to 90% selectivity for all monofluorinated dodecane and more than 30% selectivity for terminal fluorinated dodecane, which provides a novel means for preparing mono and terminal linear fluorinated alkanes. In the reaction, PAF with a large surface area is chosen as support to adsorb the linear hydrocarbon.",

keywords = "Alumium fluoride, Fluorination, N-Dodecane",

author = "Quan, {Heng Dao} and Masanori Tamura and Toshiyuki Takagi and Akira Sekiya",

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doi = "10.1016/S0022-1139(99)00134-7",

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AU - Quan, Heng Dao

AU - Tamura, Masanori

AU - Takagi, Toshiyuki

AU - Sekiya, Akira

PY - 1999/11

Y1 - 1999/11

N2 - The reaction of fluorine with n-dodecane adsorbed on porous aluminium fluoride (PAF) proceeds with up to 90% selectivity for all monofluorinated dodecane and more than 30% selectivity for terminal fluorinated dodecane, which provides a novel means for preparing mono and terminal linear fluorinated alkanes. In the reaction, PAF with a large surface area is chosen as support to adsorb the linear hydrocarbon.

AB - The reaction of fluorine with n-dodecane adsorbed on porous aluminium fluoride (PAF) proceeds with up to 90% selectivity for all monofluorinated dodecane and more than 30% selectivity for terminal fluorinated dodecane, which provides a novel means for preparing mono and terminal linear fluorinated alkanes. In the reaction, PAF with a large surface area is chosen as support to adsorb the linear hydrocarbon.

KW - Alumium fluoride

KW - Fluorination

KW - N-Dodecane

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U2 - 10.1016/S0022-1139(99)00134-7

DO - 10.1016/S0022-1139(99)00134-7

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VL - 99

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JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 2

ER -

Fluorination of n-dodecane adsorbed on porous aluminium fluoride by gaseous fluorine

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