Fluorination of n-dodecane adsorbed on porous aluminium fluoride by gaseous fluorine

Heng Dao Quan; Masanori Tamura; Toshiyuki Takagi; Akira Sekiya

doi:10.1016/S0022-1139(99)00134-7

Fluorination of n-dodecane adsorbed on porous aluminium fluoride by gaseous fluorine

Heng Dao Quan^*, Masanori Tamura, Toshiyuki Takagi, Akira Sekiya

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The reaction of fluorine with n-dodecane adsorbed on porous aluminium fluoride (PAF) proceeds with up to 90% selectivity for all monofluorinated dodecane and more than 30% selectivity for terminal fluorinated dodecane, which provides a novel means for preparing mono and terminal linear fluorinated alkanes. In the reaction, PAF with a large surface area is chosen as support to adsorb the linear hydrocarbon.

Original language	English
Pages (from-to)	167-170
Number of pages	4
Journal	Journal of Fluorine Chemistry
Volume	99
Issue number	2
DOIs	https://doi.org/10.1016/S0022-1139(99)00134-7
Publication status	Published - Nov 1999
Externally published	Yes

Keywords

Alumium fluoride
Fluorination
N-Dodecane

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10.1016/S0022-1139(99)00134-7

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Quan, H. D., Tamura, M., Takagi, T., & Sekiya, A. (1999). Fluorination of n-dodecane adsorbed on porous aluminium fluoride by gaseous fluorine. Journal of Fluorine Chemistry, 99(2), 167-170. https://doi.org/10.1016/S0022-1139(99)00134-7

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abstract = "The reaction of fluorine with n-dodecane adsorbed on porous aluminium fluoride (PAF) proceeds with up to 90% selectivity for all monofluorinated dodecane and more than 30% selectivity for terminal fluorinated dodecane, which provides a novel means for preparing mono and terminal linear fluorinated alkanes. In the reaction, PAF with a large surface area is chosen as support to adsorb the linear hydrocarbon.",

keywords = "Alumium fluoride, Fluorination, N-Dodecane",

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AU - Quan, Heng Dao

AU - Tamura, Masanori

AU - Takagi, Toshiyuki

AU - Sekiya, Akira

PY - 1999/11

Y1 - 1999/11

N2 - The reaction of fluorine with n-dodecane adsorbed on porous aluminium fluoride (PAF) proceeds with up to 90% selectivity for all monofluorinated dodecane and more than 30% selectivity for terminal fluorinated dodecane, which provides a novel means for preparing mono and terminal linear fluorinated alkanes. In the reaction, PAF with a large surface area is chosen as support to adsorb the linear hydrocarbon.

AB - The reaction of fluorine with n-dodecane adsorbed on porous aluminium fluoride (PAF) proceeds with up to 90% selectivity for all monofluorinated dodecane and more than 30% selectivity for terminal fluorinated dodecane, which provides a novel means for preparing mono and terminal linear fluorinated alkanes. In the reaction, PAF with a large surface area is chosen as support to adsorb the linear hydrocarbon.

KW - Alumium fluoride

KW - Fluorination

KW - N-Dodecane

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IS - 2

ER -

Fluorination of n-dodecane adsorbed on porous aluminium fluoride by gaseous fluorine

Abstract

Keywords

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