Fluorination of etheric substrates adsorbed on porous aluminium fluoride by gaseous fluorine

Heng Dao Quan*, Masanori Tamura, Junji Murata, Ren Xiao Gao, Akira Sekiya

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

7 引用 (Scopus)

摘要

A novel fluorination procedure of etheric substrates adsorbed on porous aluminium fluoride (PAF) using gaseous fluorine has been investigated. The reaction of ethyl 1,1,2,2-tetrafluoroethylether 1 and 2-chloro-1,1,2-trifluoroethylmethylether 9 with fluorine proceeds with upto 58% selectivity for α-monofluorinated 1 and 96% selectivity for α-monofluorinated 9. At the same time, charring can be avoided in the fluorination process.

源语言英语
页(从-至)121-125
页数5
期刊Journal of Fluorine Chemistry
106
2
DOI
出版状态已出版 - 12月 2000
已对外发布

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