Fluorination of etheric substrates adsorbed on porous aluminium fluoride by gaseous fluorine

Heng Dao Quan; Masanori Tamura; Junji Murata; Ren Xiao Gao; Akira Sekiya

doi:10.1016/S0022-1139(00)00317-1

Fluorination of etheric substrates adsorbed on porous aluminium fluoride by gaseous fluorine

Heng Dao Quan^*, Masanori Tamura, Junji Murata, Ren Xiao Gao, Akira Sekiya

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

A novel fluorination procedure of etheric substrates adsorbed on porous aluminium fluoride (PAF) using gaseous fluorine has been investigated. The reaction of ethyl 1,1,2,2-tetrafluoroethylether 1 and 2-chloro-1,1,2-trifluoroethylmethylether 9 with fluorine proceeds with upto 58% selectivity for α-monofluorinated 1 and 96% selectivity for α-monofluorinated 9. At the same time, charring can be avoided in the fluorination process.

Original language	English
Pages (from-to)	121-125
Number of pages	5
Journal	Journal of Fluorine Chemistry
Volume	106
Issue number	2
DOIs	https://doi.org/10.1016/S0022-1139(00)00317-1
Publication status	Published - Dec 2000
Externally published	Yes

Keywords

2-chloro-1,1,2-trifluoroethylmethylether
Ethyl 1,1,2,2-tetrafluoroethylether
Fluorination
Porous aluminium fluoride

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10.1016/S0022-1139(00)00317-1

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Quan, H. D., Tamura, M., Murata, J., Gao, R. X., & Sekiya, A. (2000). Fluorination of etheric substrates adsorbed on porous aluminium fluoride by gaseous fluorine. Journal of Fluorine Chemistry, 106(2), 121-125. https://doi.org/10.1016/S0022-1139(00)00317-1

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title = "Fluorination of etheric substrates adsorbed on porous aluminium fluoride by gaseous fluorine",

abstract = "A novel fluorination procedure of etheric substrates adsorbed on porous aluminium fluoride (PAF) using gaseous fluorine has been investigated. The reaction of ethyl 1,1,2,2-tetrafluoroethylether 1 and 2-chloro-1,1,2-trifluoroethylmethylether 9 with fluorine proceeds with upto 58% selectivity for α-monofluorinated 1 and 96% selectivity for α-monofluorinated 9. At the same time, charring can be avoided in the fluorination process.",

keywords = "2-chloro-1,1,2-trifluoroethylmethylether, Ethyl 1,1,2,2-tetrafluoroethylether, Fluorination, Porous aluminium fluoride",

author = "Quan, {Heng Dao} and Masanori Tamura and Junji Murata and Gao, {Ren Xiao} and Akira Sekiya",

year = "2000",

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doi = "10.1016/S0022-1139(00)00317-1",

language = "English",

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journal = "Journal of Fluorine Chemistry",

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T1 - Fluorination of etheric substrates adsorbed on porous aluminium fluoride by gaseous fluorine

AU - Quan, Heng Dao

AU - Tamura, Masanori

AU - Murata, Junji

AU - Gao, Ren Xiao

AU - Sekiya, Akira

PY - 2000/12

Y1 - 2000/12

N2 - A novel fluorination procedure of etheric substrates adsorbed on porous aluminium fluoride (PAF) using gaseous fluorine has been investigated. The reaction of ethyl 1,1,2,2-tetrafluoroethylether 1 and 2-chloro-1,1,2-trifluoroethylmethylether 9 with fluorine proceeds with upto 58% selectivity for α-monofluorinated 1 and 96% selectivity for α-monofluorinated 9. At the same time, charring can be avoided in the fluorination process.

AB - A novel fluorination procedure of etheric substrates adsorbed on porous aluminium fluoride (PAF) using gaseous fluorine has been investigated. The reaction of ethyl 1,1,2,2-tetrafluoroethylether 1 and 2-chloro-1,1,2-trifluoroethylmethylether 9 with fluorine proceeds with upto 58% selectivity for α-monofluorinated 1 and 96% selectivity for α-monofluorinated 9. At the same time, charring can be avoided in the fluorination process.

KW - 2-chloro-1,1,2-trifluoroethylmethylether

KW - Ethyl 1,1,2,2-tetrafluoroethylether

KW - Fluorination

KW - Porous aluminium fluoride

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M3 - Article

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SN - 0022-1139

VL - 106

SP - 121

EP - 125

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 2

ER -

Fluorination of etheric substrates adsorbed on porous aluminium fluoride by gaseous fluorine

Abstract

Keywords

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