Abstract
A novel fluorination procedure of etheric substrates adsorbed on porous aluminium fluoride (PAF) using gaseous fluorine has been investigated. The reaction of ethyl 1,1,2,2-tetrafluoroethylether 1 and 2-chloro-1,1,2-trifluoroethylmethylether 9 with fluorine proceeds with upto 58% selectivity for α-monofluorinated 1 and 96% selectivity for α-monofluorinated 9. At the same time, charring can be avoided in the fluorination process.
Original language | English |
---|---|
Pages (from-to) | 121-125 |
Number of pages | 5 |
Journal | Journal of Fluorine Chemistry |
Volume | 106 |
Issue number | 2 |
DOIs | |
Publication status | Published - Dec 2000 |
Externally published | Yes |
Keywords
- 2-chloro-1,1,2-trifluoroethylmethylether
- Ethyl 1,1,2,2-tetrafluoroethylether
- Fluorination
- Porous aluminium fluoride