Fluorination of chlorofluoroether using catalysts supported by porous aluminum fluoride

Akira Sekiya, Heng Dao Quan, Masanori Tamura, Ren Xiao Gao, Junji Murata

科研成果: 期刊稿件文章同行评审

10 引用 (Scopus)

摘要

Reaction of 1,2-dichloro-1,1,2-trifluoro-2-methoxyethane with anhydrous hydrogen fluoride (AHF) was investigated in the presence of metal fluorides supported on porous aluminum fluoride (PAF). 2-Chloro-1,1,2,2-tetrafluoro-2-methoxyethane, a new compound, was prepared in 85% yield in the presence of CoF2/PAF. Methyl chlorodifluoroacetate was also obtained and its formation was discussed.

源语言英语
页(从-至)145-148
页数4
期刊Journal of Fluorine Chemistry
112
1
DOI
出版状态已出版 - 2001
已对外发布

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