Fluorination of chlorofluoroether using catalysts supported by porous aluminum fluoride

Akira Sekiya; Heng Dao Quan; Masanori Tamura; Ren Xiao Gao; Junji Murata

doi:10.1016/S0022-1139(01)00483-3

Fluorination of chlorofluoroether using catalysts supported by porous aluminum fluoride

Akira Sekiya, Heng Dao Quan, Masanori Tamura, Ren Xiao Gao, Junji Murata

National Institute of Advanced Industrial Science and Technology

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

Reaction of 1,2-dichloro-1,1,2-trifluoro-2-methoxyethane with anhydrous hydrogen fluoride (AHF) was investigated in the presence of metal fluorides supported on porous aluminum fluoride (PAF). 2-Chloro-1,1,2,2-tetrafluoro-2-methoxyethane, a new compound, was prepared in 85% yield in the presence of CoF₂/PAF. Methyl chlorodifluoroacetate was also obtained and its formation was discussed.

Original language	English
Pages (from-to)	145-148
Number of pages	4
Journal	Journal of Fluorine Chemistry
Volume	112
Issue number	1
DOIs	https://doi.org/10.1016/S0022-1139(01)00483-3
Publication status	Published - 2001
Externally published	Yes

Keywords

1,2-Dichloro-1,1,2-trifluoro-2-methoxyethane
2-Chloro-1,1,2, 2-tetrafluoro-2-methoxyethane
Methyl chlorodifluoroacetate
Porous aluminum fluoride

Access to Document

10.1016/S0022-1139(01)00483-3

Cite this

@article{b12b08e48a7541baae3f6f3436a1dea0,

title = "Fluorination of chlorofluoroether using catalysts supported by porous aluminum fluoride",

abstract = "Reaction of 1,2-dichloro-1,1,2-trifluoro-2-methoxyethane with anhydrous hydrogen fluoride (AHF) was investigated in the presence of metal fluorides supported on porous aluminum fluoride (PAF). 2-Chloro-1,1,2,2-tetrafluoro-2-methoxyethane, a new compound, was prepared in 85% yield in the presence of CoF2/PAF. Methyl chlorodifluoroacetate was also obtained and its formation was discussed.",

keywords = "1,2-Dichloro-1,1,2-trifluoro-2-methoxyethane, 2-Chloro-1,1,2, 2-tetrafluoro-2-methoxyethane, Methyl chlorodifluoroacetate, Porous aluminum fluoride",

author = "Akira Sekiya and Quan, {Heng Dao} and Masanori Tamura and Gao, {Ren Xiao} and Junji Murata",

year = "2001",

doi = "10.1016/S0022-1139(01)00483-3",

language = "English",

volume = "112",

pages = "145--148",

journal = "Journal of Fluorine Chemistry",

issn = "0022-1139",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Fluorination of chlorofluoroether using catalysts supported by porous aluminum fluoride

AU - Sekiya, Akira

AU - Quan, Heng Dao

AU - Tamura, Masanori

AU - Gao, Ren Xiao

AU - Murata, Junji

PY - 2001

Y1 - 2001

N2 - Reaction of 1,2-dichloro-1,1,2-trifluoro-2-methoxyethane with anhydrous hydrogen fluoride (AHF) was investigated in the presence of metal fluorides supported on porous aluminum fluoride (PAF). 2-Chloro-1,1,2,2-tetrafluoro-2-methoxyethane, a new compound, was prepared in 85% yield in the presence of CoF2/PAF. Methyl chlorodifluoroacetate was also obtained and its formation was discussed.

AB - Reaction of 1,2-dichloro-1,1,2-trifluoro-2-methoxyethane with anhydrous hydrogen fluoride (AHF) was investigated in the presence of metal fluorides supported on porous aluminum fluoride (PAF). 2-Chloro-1,1,2,2-tetrafluoro-2-methoxyethane, a new compound, was prepared in 85% yield in the presence of CoF2/PAF. Methyl chlorodifluoroacetate was also obtained and its formation was discussed.

KW - 1,2-Dichloro-1,1,2-trifluoro-2-methoxyethane

KW - 2-Chloro-1,1,2, 2-tetrafluoro-2-methoxyethane

KW - Methyl chlorodifluoroacetate

KW - Porous aluminum fluoride

UR - http://www.scopus.com/inward/record.url?scp=0035160368&partnerID=8YFLogxK

U2 - 10.1016/S0022-1139(01)00483-3

DO - 10.1016/S0022-1139(01)00483-3

M3 - Article

AN - SCOPUS:0035160368

SN - 0022-1139

VL - 112

SP - 145

EP - 148

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

IS - 1

ER -

Fluorination of chlorofluoroether using catalysts supported by porous aluminum fluoride

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this