Direct conversion of methane into formaldehyde mediated by [Al 2O 3] .+ at room temperature

Zhe Chen Wang, Nicolas Dietl, Robert Kretschmer, Jia Bi Ma, Thomas Weiske, Maria Schlangen*, Helmut Schwarz

*此作品的通讯作者

科研成果: 期刊稿件文章同行评审

90 引用 (Scopus)

摘要

Just one step: Reactivity studies demonstrate that in the gas phase [Al 2O 3] .+ clusters can efficiently conduct the direct conversion of CH 4 into CH 2O at room temperature (see scheme). The reaction mechanism is highly complex involving oxygen-atom transfer and a double hydrogen-atom transfer.

源语言英语
页(从-至)3703-3707
页数5
期刊Angewandte Chemie - International Edition
51
15
DOI
出版状态已出版 - 10 4月 2012
已对外发布

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