Direct conversion of methane into formaldehyde mediated by [Al 2O 3] .+ at room temperature

Zhe Chen Wang; Nicolas Dietl; Robert Kretschmer; Jia Bi Ma; Thomas Weiske; Maria Schlangen; Helmut Schwarz

doi:10.1002/anie.201200015

Direct conversion of methane into formaldehyde mediated by [Al ₂O ₃] ^.+ at room temperature

Zhe Chen Wang, Nicolas Dietl, Robert Kretschmer, Jia Bi Ma, Thomas Weiske, Maria Schlangen^*, Helmut Schwarz

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

90 Citations (Scopus)

Abstract

Just one step: Reactivity studies demonstrate that in the gas phase [Al ₂O ₃] ^.+ clusters can efficiently conduct the direct conversion of CH ₄ into CH ₂O at room temperature (see scheme). The reaction mechanism is highly complex involving oxygen-atom transfer and a double hydrogen-atom transfer.

Original language	English
Pages (from-to)	3703-3707
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	51
Issue number	15
DOIs	https://doi.org/10.1002/anie.201200015
Publication status	Published - 10 Apr 2012
Externally published	Yes

Keywords

density functional calculations
gas-phase reactions
mass spectrometry
radical ions
reaction mechanisms

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10.1002/anie.201200015

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abstract = "Just one step: Reactivity studies demonstrate that in the gas phase [Al 2O 3] .+ clusters can efficiently conduct the direct conversion of CH 4 into CH 2O at room temperature (see scheme). The reaction mechanism is highly complex involving oxygen-atom transfer and a double hydrogen-atom transfer.",

keywords = "density functional calculations, gas-phase reactions, mass spectrometry, radical ions, reaction mechanisms",

author = "Wang, {Zhe Chen} and Nicolas Dietl and Robert Kretschmer and Ma, {Jia Bi} and Thomas Weiske and Maria Schlangen and Helmut Schwarz",

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AU - Wang, Zhe Chen

AU - Dietl, Nicolas

AU - Kretschmer, Robert

AU - Ma, Jia Bi

AU - Weiske, Thomas

AU - Schlangen, Maria

AU - Schwarz, Helmut

PY - 2012/4/10

Y1 - 2012/4/10

N2 - Just one step: Reactivity studies demonstrate that in the gas phase [Al 2O 3] .+ clusters can efficiently conduct the direct conversion of CH 4 into CH 2O at room temperature (see scheme). The reaction mechanism is highly complex involving oxygen-atom transfer and a double hydrogen-atom transfer.

AB - Just one step: Reactivity studies demonstrate that in the gas phase [Al 2O 3] .+ clusters can efficiently conduct the direct conversion of CH 4 into CH 2O at room temperature (see scheme). The reaction mechanism is highly complex involving oxygen-atom transfer and a double hydrogen-atom transfer.

KW - density functional calculations

KW - gas-phase reactions

KW - mass spectrometry

KW - radical ions

KW - reaction mechanisms

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M3 - Article

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SN - 1433-7851

VL - 51

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JO - Angewandte Chemie - International Edition

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ER -

Direct conversion of methane into formaldehyde mediated by [Al ₂O ₃] ^.+ at room temperature

Abstract

Keywords

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