摘要
The title complex, [Ni2(N3)4(C14H12N2)2], is a centrosymmetric dimer in which each NiII atom is coordinated by five N atoms (two from a 2,9-dimethyl-1,10-phenanthroline ligand, two from the bridging azide group and one from the terminal azide) in a slightly distorted square-pyramidal geometry. The Ni⋯Ni distance is 3.2532 (9) Å. In the crystal structure, mol-ecules are linked into one-dimensional chains by C - H⋯N hydrogen bonds and π-π stacking inter-actions [π-π interaction distance = 3.6215 (16) Å].
源语言 | 英语 |
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页(从-至) | m2211 |
期刊 | Acta Crystallographica Section E: Structure Reports Online |
卷 | 63 |
期 | 8 |
DOI | |
出版状态 | 已出版 - 31 7月 2007 |
指纹
探究 'Di -μazido-k4 N:N-bis-[(azido-kN)(2,9-dimethyl-1,10- phenanthroline-k2 N,N′)nickel(II)]' 的科研主题。它们共同构成独一无二的指纹。引用此
Li, L. L., & Liu, T. F. (2007). Di -μazido-k4 N:N-bis-[(azido-kN)(2,9-dimethyl-1,10- phenanthroline-k2 N,N′)nickel(II)]. Acta Crystallographica Section E: Structure Reports Online, 63(8), m2211. https://doi.org/10.1107/S1600536807035313