TY - JOUR
T1 - Di -μazido-k4 N:N-bis-[(azido-kN)(2,9-dimethyl-1,10- phenanthroline-k2 N,N′)nickel(II)]
AU - Li, Ling Ling
AU - Liu, Tian Fu
PY - 2007/7/31
Y1 - 2007/7/31
N2 - The title complex, [Ni2(N3)4(C14H12N2)2], is a centrosymmetric dimer in which each NiII atom is coordinated by five N atoms (two from a 2,9-dimethyl-1,10-phenanthroline ligand, two from the bridging azide group and one from the terminal azide) in a slightly distorted square-pyramidal geometry. The Ni⋯Ni distance is 3.2532 (9) Å. In the crystal structure, mol-ecules are linked into one-dimensional chains by C - H⋯N hydrogen bonds and π-π stacking inter-actions [π-π interaction distance = 3.6215 (16) Å].
AB - The title complex, [Ni2(N3)4(C14H12N2)2], is a centrosymmetric dimer in which each NiII atom is coordinated by five N atoms (two from a 2,9-dimethyl-1,10-phenanthroline ligand, two from the bridging azide group and one from the terminal azide) in a slightly distorted square-pyramidal geometry. The Ni⋯Ni distance is 3.2532 (9) Å. In the crystal structure, mol-ecules are linked into one-dimensional chains by C - H⋯N hydrogen bonds and π-π stacking inter-actions [π-π interaction distance = 3.6215 (16) Å].
UR - http://www.scopus.com/inward/record.url?scp=34547818210&partnerID=8YFLogxK
U2 - 10.1107/S1600536807035313
DO - 10.1107/S1600536807035313
M3 - Article
AN - SCOPUS:34547818210
SN - 1600-5368
VL - 63
SP - m2211
JO - Acta Crystallographica Section E: Structure Reports Online
JF - Acta Crystallographica Section E: Structure Reports Online
IS - 8
ER -