TY - JOUR
T1 - (C6H16N2)Zn3(HPO 3)4H2O
T2 - A new layered zinc phosphite templated by diprotonated trans-1,4-diaminocyclohexane
AU - Wang, Yu
AU - Yu, Jihong
AU - Li, Yi
AU - Du, Yu
AU - Xu, Ruren
AU - Ye, Ling
PY - 2003/2/1
Y1 - 2003/2/1
N2 - Employing trans-1,4-diaminocyclohexane (trans-1,4-DACH) as a template, a new two-dimensional layered zinc phosphite (C6H16N 2)Zn3(HPO3)4H2O (1) has been prepared hydrothermally. Single-crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group P21/n with a=10.458(2)Å, b=14.720(3)Å, c=13.079(3)Å, β=97.93(3) °, V=1994.1(7)Å3, Z=4, R1=0.0349 (I>2σ(I)) and wR2=0.0605 (all data). The inorganic layer is built up by alternation of ZnO4 tetrahedra and HPO3 pseudo pyramids forming a 4.6.8-net. The sheet is featured by a series of capped six-membered rings. The diprotonated trans-1,4-DACH molecules reside in the interlayer region and interact with the inorganic network through H-bonds.
AB - Employing trans-1,4-diaminocyclohexane (trans-1,4-DACH) as a template, a new two-dimensional layered zinc phosphite (C6H16N 2)Zn3(HPO3)4H2O (1) has been prepared hydrothermally. Single-crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group P21/n with a=10.458(2)Å, b=14.720(3)Å, c=13.079(3)Å, β=97.93(3) °, V=1994.1(7)Å3, Z=4, R1=0.0349 (I>2σ(I)) and wR2=0.0605 (all data). The inorganic layer is built up by alternation of ZnO4 tetrahedra and HPO3 pseudo pyramids forming a 4.6.8-net. The sheet is featured by a series of capped six-membered rings. The diprotonated trans-1,4-DACH molecules reside in the interlayer region and interact with the inorganic network through H-bonds.
KW - H-bonds
KW - Hydrothermal synthesis
KW - Layer
KW - Structure
KW - Zinc phosphite
UR - http://www.scopus.com/inward/record.url?scp=1642390034&partnerID=8YFLogxK
U2 - 10.1016/S0022-4596(02)00090-7
DO - 10.1016/S0022-4596(02)00090-7
M3 - Article
AN - SCOPUS:1642390034
SN - 0022-4596
VL - 170
SP - 303
EP - 307
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
IS - 2
ER -