(C6H16N2)Zn3(HPO 3)4H2O: A new layered zinc phosphite templated by diprotonated trans-1,4-diaminocyclohexane

Yu Wang; Jihong Yu; Yi Li; Yu Du; Ruren Xu; Ling Ye

doi:10.1016/S0022-4596(02)00090-7

(C₆H₁₆N₂)Zn₃(HPO ₃)₄H₂O: A new layered zinc phosphite templated by diprotonated trans-1,4-diaminocyclohexane

Yu Wang, Jihong Yu^*, Yi Li, Yu Du, Ruren Xu, Ling Ye

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

Employing trans-1,4-diaminocyclohexane (trans-1,4-DACH) as a template, a new two-dimensional layered zinc phosphite (C₆H₁₆N ₂)Zn₃(HPO₃)₄H₂O (1) has been prepared hydrothermally. Single-crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group P2₁/n with a=10.458(2)Å, b=14.720(3)Å, c=13.079(3)Å, β=97.93(3) °, V=1994.1(7)Å³, Z=4, R₁=0.0349 (I>2σ(I)) and wR₂=0.0605 (all data). The inorganic layer is built up by alternation of ZnO₄ tetrahedra and HPO₃ pseudo pyramids forming a 4.6.8-net. The sheet is featured by a series of capped six-membered rings. The diprotonated trans-1,4-DACH molecules reside in the interlayer region and interact with the inorganic network through H-bonds.

Original language	English
Pages (from-to)	303-307
Number of pages	5
Journal	Journal of Solid State Chemistry
Volume	170
Issue number	2
DOIs	https://doi.org/10.1016/S0022-4596(02)00090-7
Publication status	Published - 1 Feb 2003
Externally published	Yes

Keywords

H-bonds
Hydrothermal synthesis
Layer
Structure
Zinc phosphite

Access to Document

10.1016/S0022-4596(02)00090-7

Cite this

Wang, Y., Yu, J., Li, Y., Du, Y., Xu, R., & Ye, L. (2003). (C₆H₁₆N₂)Zn₃(HPO ₃)₄H₂O: A new layered zinc phosphite templated by diprotonated trans-1,4-diaminocyclohexane. Journal of Solid State Chemistry, 170(2), 303-307. https://doi.org/10.1016/S0022-4596(02)00090-7

@article{adf647bb14354e729551fe768808dfef,

title = "(C6H16N2)Zn3(HPO 3)4H2O: A new layered zinc phosphite templated by diprotonated trans-1,4-diaminocyclohexane",

abstract = "Employing trans-1,4-diaminocyclohexane (trans-1,4-DACH) as a template, a new two-dimensional layered zinc phosphite (C6H16N 2)Zn3(HPO3)4H2O (1) has been prepared hydrothermally. Single-crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group P21/n with a=10.458(2){\AA}, b=14.720(3){\AA}, c=13.079(3){\AA}, β=97.93(3) °, V=1994.1(7){\AA}3, Z=4, R1=0.0349 (I>2σ(I)) and wR2=0.0605 (all data). The inorganic layer is built up by alternation of ZnO4 tetrahedra and HPO3 pseudo pyramids forming a 4.6.8-net. The sheet is featured by a series of capped six-membered rings. The diprotonated trans-1,4-DACH molecules reside in the interlayer region and interact with the inorganic network through H-bonds.",

keywords = "H-bonds, Hydrothermal synthesis, Layer, Structure, Zinc phosphite",

author = "Yu Wang and Jihong Yu and Yi Li and Yu Du and Ruren Xu and Ling Ye",

year = "2003",

month = feb,

day = "1",

doi = "10.1016/S0022-4596(02)00090-7",

language = "English",

volume = "170",

pages = "303--307",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

number = "2",

}

TY - JOUR

T1 - (C6H16N2)Zn3(HPO 3)4H2O

T2 - A new layered zinc phosphite templated by diprotonated trans-1,4-diaminocyclohexane

AU - Wang, Yu

AU - Yu, Jihong

AU - Li, Yi

AU - Du, Yu

AU - Xu, Ruren

AU - Ye, Ling

PY - 2003/2/1

Y1 - 2003/2/1

N2 - Employing trans-1,4-diaminocyclohexane (trans-1,4-DACH) as a template, a new two-dimensional layered zinc phosphite (C6H16N 2)Zn3(HPO3)4H2O (1) has been prepared hydrothermally. Single-crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group P21/n with a=10.458(2)Å, b=14.720(3)Å, c=13.079(3)Å, β=97.93(3) °, V=1994.1(7)Å3, Z=4, R1=0.0349 (I>2σ(I)) and wR2=0.0605 (all data). The inorganic layer is built up by alternation of ZnO4 tetrahedra and HPO3 pseudo pyramids forming a 4.6.8-net. The sheet is featured by a series of capped six-membered rings. The diprotonated trans-1,4-DACH molecules reside in the interlayer region and interact with the inorganic network through H-bonds.

AB - Employing trans-1,4-diaminocyclohexane (trans-1,4-DACH) as a template, a new two-dimensional layered zinc phosphite (C6H16N 2)Zn3(HPO3)4H2O (1) has been prepared hydrothermally. Single-crystal X-ray diffraction analysis shows that it crystallizes in the monoclinic space group P21/n with a=10.458(2)Å, b=14.720(3)Å, c=13.079(3)Å, β=97.93(3) °, V=1994.1(7)Å3, Z=4, R1=0.0349 (I>2σ(I)) and wR2=0.0605 (all data). The inorganic layer is built up by alternation of ZnO4 tetrahedra and HPO3 pseudo pyramids forming a 4.6.8-net. The sheet is featured by a series of capped six-membered rings. The diprotonated trans-1,4-DACH molecules reside in the interlayer region and interact with the inorganic network through H-bonds.

KW - H-bonds

KW - Hydrothermal synthesis

KW - Layer

KW - Structure

KW - Zinc phosphite

UR - http://www.scopus.com/inward/record.url?scp=1642390034&partnerID=8YFLogxK

U2 - 10.1016/S0022-4596(02)00090-7

DO - 10.1016/S0022-4596(02)00090-7

M3 - Article

AN - SCOPUS:1642390034

SN - 0022-4596

VL - 170

SP - 303

EP - 307

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 2

ER -

(C₆H₁₆N₂)Zn₃(HPO ₃)₄H₂O: A new layered zinc phosphite templated by diprotonated trans-1,4-diaminocyclohexane

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this