TY - JOUR
T1 - Characterization of Hydrazinium 3,5-Dinitroamine-1,2,4-triazole
AU - Cui, Kejian
AU - Meng, Zihui
AU - Xu, Zhibin
AU - Xue, Min
AU - Lin, Zhihui
AU - Wang, Bozhou
AU - Ge, Zhongxue
AU - Qin, Guangmin
PY - 2014/5
Y1 - 2014/5
N2 - The structure of hydrazinium 3,5-dinitroamine-1,2,4-triazole (HDNAT) was investigated with infrared (IR), mass spectrometry, 13C-NMR, scanning electron microscopy (SEM), and X-ray crystallography. The crystal density of HDNAT was determined as 1.91 g/cm3 using X-ray diffraction. The crystal belongs to a monoclinic system with the space group P2(1). The thermal decomposition process of HDNAT was investigated via thermogravimetry-differential thermal analysis (TG-DTA) at a heating rate of 10 K/min and differential scanning calorimetry (DSC) under nonisothermal conditions. The decomposition kinetic and thermodynamic parameters were obtained by the Kissinger and Ozawa method. HDNAT can be analyzed by using a C18 high-performance liquid chromatography (HPLC) column with water: acetonitrile: trifluoroacetic acid (97/3/0.1, v/v/v) as the mobile phase and a capacity factor of 1.33.
AB - The structure of hydrazinium 3,5-dinitroamine-1,2,4-triazole (HDNAT) was investigated with infrared (IR), mass spectrometry, 13C-NMR, scanning electron microscopy (SEM), and X-ray crystallography. The crystal density of HDNAT was determined as 1.91 g/cm3 using X-ray diffraction. The crystal belongs to a monoclinic system with the space group P2(1). The thermal decomposition process of HDNAT was investigated via thermogravimetry-differential thermal analysis (TG-DTA) at a heating rate of 10 K/min and differential scanning calorimetry (DSC) under nonisothermal conditions. The decomposition kinetic and thermodynamic parameters were obtained by the Kissinger and Ozawa method. HDNAT can be analyzed by using a C18 high-performance liquid chromatography (HPLC) column with water: acetonitrile: trifluoroacetic acid (97/3/0.1, v/v/v) as the mobile phase and a capacity factor of 1.33.
KW - characterization
KW - energetic material
KW - hydrazinium 3,5-dinitroamine-1,2,4-triazole
KW - triazole
UR - http://www.scopus.com/inward/record.url?scp=84899652979&partnerID=8YFLogxK
U2 - 10.1080/07370652.2013.828246
DO - 10.1080/07370652.2013.828246
M3 - Article
AN - SCOPUS:84899652979
SN - 0737-0652
VL - 32
SP - S60-S70
JO - Journal of Energetic Materials
JF - Journal of Energetic Materials
IS - SUP1
ER -