TY - JOUR
T1 - Cadmium(II)-1,4-phenylenediacetate complex with green luminescence
AU - Xu, Yan Qing
AU - Zhou, You Fu
AU - Yuan, Da Qiang
AU - Hong, Mao Chun
PY - 2006
Y1 - 2006
N2 - The title complex, formulated as {[Cd(pda)(phen)]·3H 2O}n 1 (pda = 1,4-phenylenediacetate, phen = 1,10′-phenanthroline), has been hydrothermally synthesized and determined by X-ray crystallography. Crystallographic data: triclinic, space group P1, a = 10.375 (7), b = 10.435(1), c = 12.040(1) Å, α = 68.503(1), β = 86.371(1), γ = 66.231(1)°, Mr = 538.82, V = 1104.5(8) Å3, Z = 2, Dc = 1.620 g/cm3, μ = 1.035 mm-1, F(000) = 544, the final R = 0.0380 and wR = 0.0985 (w = 1/[σ2(Fo2) + (0.0559P)2 + 1.5319P], where P = (Fo2 + 2Fc2)/3) based on 3444 observed reflections with I >2σ(I). Complex 1 features a two-dimensional layer. Fluorescent analysis reveals that it exhibits intense green luminescence with the maximum at around 516 nm.
AB - The title complex, formulated as {[Cd(pda)(phen)]·3H 2O}n 1 (pda = 1,4-phenylenediacetate, phen = 1,10′-phenanthroline), has been hydrothermally synthesized and determined by X-ray crystallography. Crystallographic data: triclinic, space group P1, a = 10.375 (7), b = 10.435(1), c = 12.040(1) Å, α = 68.503(1), β = 86.371(1), γ = 66.231(1)°, Mr = 538.82, V = 1104.5(8) Å3, Z = 2, Dc = 1.620 g/cm3, μ = 1.035 mm-1, F(000) = 544, the final R = 0.0380 and wR = 0.0985 (w = 1/[σ2(Fo2) + (0.0559P)2 + 1.5319P], where P = (Fo2 + 2Fc2)/3) based on 3444 observed reflections with I >2σ(I). Complex 1 features a two-dimensional layer. Fluorescent analysis reveals that it exhibits intense green luminescence with the maximum at around 516 nm.
KW - Cadmium(II)
KW - Coordination polymer
KW - Crystal structure
KW - Fluorescence
UR - http://www.scopus.com/inward/record.url?scp=33745846767&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:33745846767
SN - 0254-5861
VL - 25
SP - 704
EP - 708
JO - Jiegou Huaxue
JF - Jiegou Huaxue
IS - 6
ER -