Cadmium(II)-1,4-phenylenediacetate complex with green luminescence

Yan Qing Xu; You Fu Zhou; Da Qiang Yuan; Mao Chun Hong

Cadmium(II)-1,4-phenylenediacetate complex with green luminescence

Yan Qing Xu, You Fu Zhou^*, Da Qiang Yuan, Mao Chun Hong

^*Corresponding author for this work

CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

The title complex, formulated as {[Cd(pda)(phen)]·3H ₂O}_n 1 (pda = 1,4-phenylenediacetate, phen = 1,10′-phenanthroline), has been hydrothermally synthesized and determined by X-ray crystallography. Crystallographic data: triclinic, space group P1, a = 10.375 (7), b = 10.435(1), c = 12.040(1) Å, α = 68.503(1), β = 86.371(1), γ = 66.231(1)°, M_r = 538.82, V = 1104.5(8) Å³, Z = 2, D_c = 1.620 g/cm³, μ = 1.035 mm^-1, F(000) = 544, the final R = 0.0380 and wR = 0.0985 (w = 1/[σ²(F_o²) + (0.0559P)² + 1.5319P], where P = (F_o² + 2F_c²)/3) based on 3444 observed reflections with I >2σ(I). Complex 1 features a two-dimensional layer. Fluorescent analysis reveals that it exhibits intense green luminescence with the maximum at around 516 nm.

Original language	English
Pages (from-to)	704-708
Number of pages	5
Journal	Jiegou Huaxue
Volume	25
Issue number	6
Publication status	Published - 2006
Externally published	Yes

Keywords

Cadmium(II)
Coordination polymer
Crystal structure
Fluorescence

Cite this

@article{94949b3e665f4101a92acbdef366c40c,

title = "Cadmium(II)-1,4-phenylenediacetate complex with green luminescence",

abstract = "The title complex, formulated as {[Cd(pda)(phen)]·3H 2O}n 1 (pda = 1,4-phenylenediacetate, phen = 1,10′-phenanthroline), has been hydrothermally synthesized and determined by X-ray crystallography. Crystallographic data: triclinic, space group P1, a = 10.375 (7), b = 10.435(1), c = 12.040(1) {\AA}, α = 68.503(1), β = 86.371(1), γ = 66.231(1)°, Mr = 538.82, V = 1104.5(8) {\AA}3, Z = 2, Dc = 1.620 g/cm3, μ = 1.035 mm-1, F(000) = 544, the final R = 0.0380 and wR = 0.0985 (w = 1/[σ2(Fo2) + (0.0559P)2 + 1.5319P], where P = (Fo2 + 2Fc2)/3) based on 3444 observed reflections with I >2σ(I). Complex 1 features a two-dimensional layer. Fluorescent analysis reveals that it exhibits intense green luminescence with the maximum at around 516 nm.",

keywords = "Cadmium(II), Coordination polymer, Crystal structure, Fluorescence",

author = "Xu, {Yan Qing} and Zhou, {You Fu} and Yuan, {Da Qiang} and Hong, {Mao Chun}",

year = "2006",

language = "English",

volume = "25",

pages = "704--708",

journal = "Jiegou Huaxue",

issn = "0254-5861",

publisher = "Fujian Institute of Research of the Structure of Matter",

number = "6",

}

TY - JOUR

T1 - Cadmium(II)-1,4-phenylenediacetate complex with green luminescence

AU - Xu, Yan Qing

AU - Zhou, You Fu

AU - Yuan, Da Qiang

AU - Hong, Mao Chun

PY - 2006

Y1 - 2006

N2 - The title complex, formulated as {[Cd(pda)(phen)]·3H 2O}n 1 (pda = 1,4-phenylenediacetate, phen = 1,10′-phenanthroline), has been hydrothermally synthesized and determined by X-ray crystallography. Crystallographic data: triclinic, space group P1, a = 10.375 (7), b = 10.435(1), c = 12.040(1) Å, α = 68.503(1), β = 86.371(1), γ = 66.231(1)°, Mr = 538.82, V = 1104.5(8) Å3, Z = 2, Dc = 1.620 g/cm3, μ = 1.035 mm-1, F(000) = 544, the final R = 0.0380 and wR = 0.0985 (w = 1/[σ2(Fo2) + (0.0559P)2 + 1.5319P], where P = (Fo2 + 2Fc2)/3) based on 3444 observed reflections with I >2σ(I). Complex 1 features a two-dimensional layer. Fluorescent analysis reveals that it exhibits intense green luminescence with the maximum at around 516 nm.

AB - The title complex, formulated as {[Cd(pda)(phen)]·3H 2O}n 1 (pda = 1,4-phenylenediacetate, phen = 1,10′-phenanthroline), has been hydrothermally synthesized and determined by X-ray crystallography. Crystallographic data: triclinic, space group P1, a = 10.375 (7), b = 10.435(1), c = 12.040(1) Å, α = 68.503(1), β = 86.371(1), γ = 66.231(1)°, Mr = 538.82, V = 1104.5(8) Å3, Z = 2, Dc = 1.620 g/cm3, μ = 1.035 mm-1, F(000) = 544, the final R = 0.0380 and wR = 0.0985 (w = 1/[σ2(Fo2) + (0.0559P)2 + 1.5319P], where P = (Fo2 + 2Fc2)/3) based on 3444 observed reflections with I >2σ(I). Complex 1 features a two-dimensional layer. Fluorescent analysis reveals that it exhibits intense green luminescence with the maximum at around 516 nm.

KW - Cadmium(II)

KW - Coordination polymer

KW - Crystal structure

KW - Fluorescence

UR - http://www.scopus.com/inward/record.url?scp=33745846767&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:33745846767

SN - 0254-5861

VL - 25

SP - 704

EP - 708

JO - Jiegou Huaxue

JF - Jiegou Huaxue

IS - 6

ER -

Cadmium(II)-1,4-phenylenediacetate complex with green luminescence

Abstract

Keywords

Other files and links

Fingerprint

Cite this