Bis(1,5-diamino-4-methyl-tetrazolium)hydrazinetetrazolate: Synthesis, structure and energetic properties

Zhiyue Han; Zhihua Zhao; Zhiming Du; Chunlin He; Linshuang Zhao; Xiaomin Cong

doi:10.1039/c4ra04999c

Bis(1,5-diamino-4-methyl-tetrazolium)hydrazinetetrazolate: Synthesis, structure and energetic properties

Zhiyue Han, Zhihua Zhao, Zhiming Du^*, Chunlin He, Linshuang Zhao, Xiaomin Cong

^*此作品的通讯作者

Beijing Institute of Technology

科研成果: 期刊稿件 › 文章 › 同行评审

17 引用（Scopus）

摘要

Bis(1,5-diamino-4-methyl-tetrazolium)hydrazinetetrazolate (BMDATHBT) was synthesized for the first time from 1,5-diamino-4-methyl-tetrazolium sulfate (MDATS) and hydrazino bitetrazole barium (HBTBa·5H₂O) as raw materials. The structure was characterized by elemental analysis, IR, ¹HNMR and MS. A single crystal of BMDATHBT was cultivated. Its crystalline density was 1.660 g cm^-3. BMDATHBT has high detonation pressure and detonation velocity (P = 25.93 GPa, D = 7.839 km s^-1), which are higher than those of TNT. Its thermal and mechanical sensitivities are moderate. The thermal decomposition products are almost all gases. Therefore, it has potential application prospects as a gas generating agent, explosive and solid propellant. This journal is

源语言	英语
页（从-至）	33724-33729
页数	6
期刊	RSC Advances
卷	4
期	64
DOI	https://doi.org/10.1039/c4ra04999c
出版状态	已出版 - 2014

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T2 - Synthesis, structure and energetic properties

AU - Han, Zhiyue

AU - Zhao, Zhihua

AU - Du, Zhiming

AU - He, Chunlin

AU - Zhao, Linshuang

AU - Cong, Xiaomin

PY - 2014

Y1 - 2014

N2 - Bis(1,5-diamino-4-methyl-tetrazolium)hydrazinetetrazolate (BMDATHBT) was synthesized for the first time from 1,5-diamino-4-methyl-tetrazolium sulfate (MDATS) and hydrazino bitetrazole barium (HBTBa·5H2O) as raw materials. The structure was characterized by elemental analysis, IR, 1HNMR and MS. A single crystal of BMDATHBT was cultivated. Its crystalline density was 1.660 g cm-3. BMDATHBT has high detonation pressure and detonation velocity (P = 25.93 GPa, D = 7.839 km s-1), which are higher than those of TNT. Its thermal and mechanical sensitivities are moderate. The thermal decomposition products are almost all gases. Therefore, it has potential application prospects as a gas generating agent, explosive and solid propellant. This journal is

AB - Bis(1,5-diamino-4-methyl-tetrazolium)hydrazinetetrazolate (BMDATHBT) was synthesized for the first time from 1,5-diamino-4-methyl-tetrazolium sulfate (MDATS) and hydrazino bitetrazole barium (HBTBa·5H2O) as raw materials. The structure was characterized by elemental analysis, IR, 1HNMR and MS. A single crystal of BMDATHBT was cultivated. Its crystalline density was 1.660 g cm-3. BMDATHBT has high detonation pressure and detonation velocity (P = 25.93 GPa, D = 7.839 km s-1), which are higher than those of TNT. Its thermal and mechanical sensitivities are moderate. The thermal decomposition products are almost all gases. Therefore, it has potential application prospects as a gas generating agent, explosive and solid propellant. This journal is

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Bis(1,5-diamino-4-methyl-tetrazolium)hydrazinetetrazolate: Synthesis, structure and energetic properties

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