Bis(1,5-diamino-4-methyl-tetrazolium)hydrazinetetrazolate: Synthesis, structure and energetic properties

Zhiyue Han; Zhihua Zhao; Zhiming Du; Chunlin He; Linshuang Zhao; Xiaomin Cong

doi:10.1039/c4ra04999c

Bis(1,5-diamino-4-methyl-tetrazolium)hydrazinetetrazolate: Synthesis, structure and energetic properties

Zhiyue Han, Zhihua Zhao, Zhiming Du^*, Chunlin He, Linshuang Zhao, Xiaomin Cong

^*Corresponding author for this work

Beijing Institute of Technology

Research output: Contribution to journal › Article › peer-review

17 Citations (Scopus)

Abstract

Bis(1,5-diamino-4-methyl-tetrazolium)hydrazinetetrazolate (BMDATHBT) was synthesized for the first time from 1,5-diamino-4-methyl-tetrazolium sulfate (MDATS) and hydrazino bitetrazole barium (HBTBa·5H₂O) as raw materials. The structure was characterized by elemental analysis, IR, ¹HNMR and MS. A single crystal of BMDATHBT was cultivated. Its crystalline density was 1.660 g cm^-3. BMDATHBT has high detonation pressure and detonation velocity (P = 25.93 GPa, D = 7.839 km s^-1), which are higher than those of TNT. Its thermal and mechanical sensitivities are moderate. The thermal decomposition products are almost all gases. Therefore, it has potential application prospects as a gas generating agent, explosive and solid propellant. This journal is

Original language	English
Pages (from-to)	33724-33729
Number of pages	6
Journal	RSC Advances
Volume	4
Issue number	64
DOIs	https://doi.org/10.1039/c4ra04999c
Publication status	Published - 2014

Access to Document

10.1039/c4ra04999c

Cite this

@article{841ca58c809a422ea981c570a66f34f9,

title = "Bis(1,5-diamino-4-methyl-tetrazolium)hydrazinetetrazolate: Synthesis, structure and energetic properties",

abstract = "Bis(1,5-diamino-4-methyl-tetrazolium)hydrazinetetrazolate (BMDATHBT) was synthesized for the first time from 1,5-diamino-4-methyl-tetrazolium sulfate (MDATS) and hydrazino bitetrazole barium (HBTBa·5H2O) as raw materials. The structure was characterized by elemental analysis, IR, 1HNMR and MS. A single crystal of BMDATHBT was cultivated. Its crystalline density was 1.660 g cm-3. BMDATHBT has high detonation pressure and detonation velocity (P = 25.93 GPa, D = 7.839 km s-1), which are higher than those of TNT. Its thermal and mechanical sensitivities are moderate. The thermal decomposition products are almost all gases. Therefore, it has potential application prospects as a gas generating agent, explosive and solid propellant. This journal is",

author = "Zhiyue Han and Zhihua Zhao and Zhiming Du and Chunlin He and Linshuang Zhao and Xiaomin Cong",

year = "2014",

doi = "10.1039/c4ra04999c",

language = "English",

volume = "4",

pages = "33724--33729",

journal = "RSC Advances",

issn = "2046-2069",

publisher = "Royal Society of Chemistry",

number = "64",

}

TY - JOUR

T1 - Bis(1,5-diamino-4-methyl-tetrazolium)hydrazinetetrazolate

T2 - Synthesis, structure and energetic properties

AU - Han, Zhiyue

AU - Zhao, Zhihua

AU - Du, Zhiming

AU - He, Chunlin

AU - Zhao, Linshuang

AU - Cong, Xiaomin

PY - 2014

Y1 - 2014

N2 - Bis(1,5-diamino-4-methyl-tetrazolium)hydrazinetetrazolate (BMDATHBT) was synthesized for the first time from 1,5-diamino-4-methyl-tetrazolium sulfate (MDATS) and hydrazino bitetrazole barium (HBTBa·5H2O) as raw materials. The structure was characterized by elemental analysis, IR, 1HNMR and MS. A single crystal of BMDATHBT was cultivated. Its crystalline density was 1.660 g cm-3. BMDATHBT has high detonation pressure and detonation velocity (P = 25.93 GPa, D = 7.839 km s-1), which are higher than those of TNT. Its thermal and mechanical sensitivities are moderate. The thermal decomposition products are almost all gases. Therefore, it has potential application prospects as a gas generating agent, explosive and solid propellant. This journal is

AB - Bis(1,5-diamino-4-methyl-tetrazolium)hydrazinetetrazolate (BMDATHBT) was synthesized for the first time from 1,5-diamino-4-methyl-tetrazolium sulfate (MDATS) and hydrazino bitetrazole barium (HBTBa·5H2O) as raw materials. The structure was characterized by elemental analysis, IR, 1HNMR and MS. A single crystal of BMDATHBT was cultivated. Its crystalline density was 1.660 g cm-3. BMDATHBT has high detonation pressure and detonation velocity (P = 25.93 GPa, D = 7.839 km s-1), which are higher than those of TNT. Its thermal and mechanical sensitivities are moderate. The thermal decomposition products are almost all gases. Therefore, it has potential application prospects as a gas generating agent, explosive and solid propellant. This journal is

UR - http://www.scopus.com/inward/record.url?scp=84906223878&partnerID=8YFLogxK

U2 - 10.1039/c4ra04999c

DO - 10.1039/c4ra04999c

M3 - Article

AN - SCOPUS:84906223878

SN - 2046-2069

VL - 4

SP - 33724

EP - 33729

JO - RSC Advances

JF - RSC Advances

IS - 64

ER -

Bis(1,5-diamino-4-methyl-tetrazolium)hydrazinetetrazolate: Synthesis, structure and energetic properties

Abstract

Access to Document

Other files and links

Fingerprint

Cite this